Evaluation of the degradation of gypsum subjected to natural aging

IF 3.9 3区 工程技术 Q2 CONSTRUCTION & BUILDING TECHNOLOGY Materials and Structures Pub Date : 2025-03-25 DOI:10.1617/s11527-025-02621-0
Sheila Daiane de Souza Rodrigues, José Getúlio Gomes de Sousa, Nelson Cárdenas Olivier
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Abstract

This research aims to evaluate the properties of gypsum with and without water repellent, with water/gypsum hemihydrate ratios of 0.7 and 0.9, when subjected to natural aging in both indoor and outdoor environments. For this purpose, in addition to the characterization of the materials and evaluation of the microstructure of the samples, the axial compressive strength, total immersion water absorption, mass loss, and capillary absorption of the test specimens were assessed. The properties were evaluated before aging, at zero age, and after 6, 12, 18, 24, 30, and 36 months of aging. It was observed that the microstructure of the dihydrate presents interwoven prismatic needles. Furthermore, the presence of the water repellent was identified both in the matrix and on the surface of the material, even after 36 months. The test specimens of type GR9 and GH9 exhibited the lowest mechanical strengths and highest absorption, both in indoor and outdoor environments. The mass loss assessed in the material exposed to the outdoor environment increased over time, indicating material dissolution caused by leaching from rainfall. This research concluded that the water/gypsum hemihydrate ratio, the addition of water repellent, and the exposure environment directly influence the percentage of water absorption and the mass loss of the material. Moreover, gypsum exposed to outdoor environments requires greater protection through the combination of water repellent and painting systems to reduce its degradation and early performance loss, contributing to greater durability.

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石膏自然老化降解评估
本研究旨在评价在水/石膏半水比为0.7和0.9时,石膏在室内和室外环境中自然老化的性能。为此,除了对材料进行表征和评价试样的微观结构外,还对试件的轴向抗压强度、总浸没吸水率、质量损失和毛细吸收量进行了评估。分别在陈化前、零陈化时和陈化6、12、18、24、30和36个月后进行了性能评估。观察到二水合物的微观结构呈现出交错的棱柱状针状结构。此外,即使在36个月后,在基质和材料表面也发现了拒水剂的存在。在室内和室外环境下,GR9型和GH9型试样的机械强度最低,吸收率最高。暴露在室外环境中的材料的质量损失随着时间的推移而增加,表明降雨淋洗引起的材料溶解。本研究得出水/石膏半水比、拒水剂的添加量和暴露环境直接影响材料的吸水率和质量损失率。此外,暴露在室外环境中的石膏需要通过防水和喷漆系统的组合来提供更好的保护,以减少其降解和早期性能损失,从而提高耐久性。
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来源期刊
Materials and Structures
Materials and Structures 工程技术-材料科学:综合
CiteScore
6.40
自引率
7.90%
发文量
222
审稿时长
5.9 months
期刊介绍: Materials and Structures, the flagship publication of the International Union of Laboratories and Experts in Construction Materials, Systems and Structures (RILEM), provides a unique international and interdisciplinary forum for new research findings on the performance of construction materials. A leader in cutting-edge research, the journal is dedicated to the publication of high quality papers examining the fundamental properties of building materials, their characterization and processing techniques, modeling, standardization of test methods, and the application of research results in building and civil engineering. Materials and Structures also publishes comprehensive reports prepared by the RILEM’s technical committees.
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