{"title":"Visible light-assisted reactions of (phenyl)(trifluoromethylsulfonylimino)-λ3-iodane with alkenes","authors":"A. S. Ganin, M. Yu. Moskalik","doi":"10.1007/s11172-025-4509-6","DOIUrl":null,"url":null,"abstract":"<div><p>Visible light-assisted (<i>λ</i> = 465–470 nm) reactions of (phenyl)(trifluoromethylsulfonylimino)-λ<sup>3</sup>-iodane with alkenes gave products of sulfonamidation and cyclization. Solvent effect on the product composition was revealed. A comparison of the reactions of the title iodane with cyclohexene carried out in the presence of <i>N</i>-halosuccinimides and under blue LED-light-activation conditions (440–450 nm) revealed the differences in triflamidation reaction producing cyclic (aziridine) and linear (halo amides, halo amidines) products. Plausible reaction mechanisms were discussed.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"74 1","pages":"137 - 142"},"PeriodicalIF":1.7000,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-025-4509-6","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Visible light-assisted (λ = 465–470 nm) reactions of (phenyl)(trifluoromethylsulfonylimino)-λ3-iodane with alkenes gave products of sulfonamidation and cyclization. Solvent effect on the product composition was revealed. A comparison of the reactions of the title iodane with cyclohexene carried out in the presence of N-halosuccinimides and under blue LED-light-activation conditions (440–450 nm) revealed the differences in triflamidation reaction producing cyclic (aziridine) and linear (halo amides, halo amidines) products. Plausible reaction mechanisms were discussed.
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
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