{"title":"Absolute Helix-Sense-Selective Polymerization Using Circularly Polarized Light in One-Handed Helical Channels","authors":"Shuaishuai Huang, Masahiro Teraguchi, Takashi Kaneko, Toshiki Aoki","doi":"10.1002/marc.202500185","DOIUrl":null,"url":null,"abstract":"<p>Absolute helix-sense-selective polymerization of an achiral acetylene monomer (<b>1</b>) in one-handed helical channels created with helix-sense-selective decomposition of (±)-poly<b>1</b> using circularly polarized light is realized with no chiral compounds. In addition, the relative optical yield (%ee) of the formed oligomers is controlled by those of the one-handed helical channels.</p>","PeriodicalId":205,"journal":{"name":"Macromolecular Rapid Communications","volume":"46 15","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Rapid Communications","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/marc.202500185","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
Absolute helix-sense-selective polymerization of an achiral acetylene monomer (1) in one-handed helical channels created with helix-sense-selective decomposition of (±)-poly1 using circularly polarized light is realized with no chiral compounds. In addition, the relative optical yield (%ee) of the formed oligomers is controlled by those of the one-handed helical channels.
期刊介绍：
Macromolecular Rapid Communications publishes original research in polymer science, ranging from chemistry and physics of polymers to polymers in materials science and life sciences.
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