Eco-Friendly Synthesis of Nitrogen-Doped Fluorescent Carbon Dots from Citrus Juice for Detection of Fe3+ Ions and Anti-Counterfeiting Printing Applications.

IF 3.1 4区 化学 Q2 BIOCHEMICAL RESEARCH METHODS Journal of Fluorescence Pub Date : 2025-10-01 Epub Date: 2025-03-24 DOI:10.1007/s10895-025-04247-5
Tianbao Fang, Lei Wu, Shaoyun Huang, Ting Guo, Yafeng Deng
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Abstract

Recently, the use of natural products to synthesize of carbon dots (CDs) has received much attention. Herein, citrus juice and urea were successfully turned into nitrogen-doped carbon dots (N-CDs) via the hydrothermal-carbonization route. The synthesized N-CDs have good fluorescence luminescence performance and high optical stability. In addition, the N-CDs exhibited selective and sensitive fluorescence quenching behavior towards Fe3+ ions and the limit of detection (LOD) can reach 1.59 µM. Moreover, environmentally friendly fluorescent inks were prepared with N-CDs as fluorescent material and cellulose (HPC, HEC, HEMC, HPMC) as a binder. These fluorescent inks meet the viscosity (4000-12000 mPa·s) and surface tension (20-60 mN/m) requirements of screen printing. Fluorescent ink still maintains good fluorescence after forming a film on filter paper.

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柑橘汁中氮掺杂荧光碳点的环保合成及其在Fe3+离子检测和防伪印刷中的应用。
近年来,利用天然产物合成碳点受到了广泛关注。本研究通过水热碳化的方法成功地将柑橘汁和尿素转化为氮掺杂碳点(N-CDs)。合成的N-CDs具有良好的荧光发光性能和较高的光学稳定性。此外,N-CDs对Fe3+离子表现出选择性和敏感的荧光猝灭行为,检出限(LOD)可达1.59µM。以N-CDs为荧光材料,纤维素(HPC、HEC、HEMC、HPMC)为粘合剂制备了环保型荧光油墨。这些荧光油墨满足丝网印刷粘度(4000-12000 mPa·s)和表面张力(20-60 mN/m)要求。荧光油墨在滤纸上形成薄膜后仍能保持良好的荧光。
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来源期刊
Journal of Fluorescence
Journal of Fluorescence 化学-分析化学
CiteScore
4.60
自引率
7.40%
发文量
203
审稿时长
5.4 months
期刊介绍: Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.
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