Addressing plastic pollution: A 3D-printed porous PAC scaffold for effective nanoplastic removal

IF 8.1 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES Chemosphere Pub Date : 2025-03-27 DOI:10.1016/j.chemosphere.2025.144351
Namyeon Kim , Da-Yeon Kim , Yunsoo Chang , Eui-Man Jung , Seung-Woo Lee , Eun-Hee Lee
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Abstract

The extensive presence of nanoplastics has raised concerns about their effects on ecosystems and human health. Because of the heightened ecological and biological risks posed by nanoplastics, effective removal strategies for these particles are essential. This study focuses on the use of additive manufacturing techniques to fabricate a three-dimensional (3D) structure with integrated powdered activated carbon (PAC) as an active adsorbent for the removal of various types of polymer nanoplastics. The 3D-printed porous PAC scaffold was characterized using various analysis methods, and its adsorption kinetics and mechanisms for polystyrene (PS) nanoplastics were elucidated. The 3D PAC's versatility was verified against several other nanoplastics, including polyethylene terephthalate, low-density polyethylene, polypropylene, and polyvinyl chloride. The results demonstrated that the 3D PAC scaffold effectively adsorbs PS nanoplastics through pore filling and chemical processes and that the adsorption exhibits pseudo-first-order kinetics and conforms to the Langmuir isotherm model. The 3D PAC maintained its adsorption performance under various environmental conditions and exhibited promising results when used to remove nanoplastics from real freshwater samples. This research demonstrates the potential of 3D-printed PACs to address the growing challenge of plastic pollution.

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解决塑料污染:用于有效去除纳米塑料的3d打印多孔PAC支架
纳米塑料的广泛存在引起了人们对其对生态系统和人类健康影响的担忧。由于纳米塑料带来的生态和生物风险增加,有效的去除这些颗粒的策略是必不可少的。本研究的重点是使用增材制造技术,以集成粉末活性炭(PAC)作为活性吸附剂,制造三维(3D)结构,以去除各种类型的聚合物纳米塑料。采用多种分析方法对3d打印多孔PAC支架进行了表征,并对其对聚苯乙烯(PS)纳米塑料的吸附动力学和机理进行了研究。3D PAC的多功能性与其他几种纳米塑料进行了对比,包括聚对苯二甲酸乙二醇酯、低密度聚乙烯、聚丙烯和聚氯乙烯。结果表明,三维PAC支架通过孔隙填充和化学过程对PS纳米塑料进行了有效吸附,吸附过程符合Langmuir等温线模型,具有准一级动力学特征。3D PAC在各种环境条件下都保持了良好的吸附性能,并在实际淡水样品中表现出了良好的去除纳米塑料的效果。这项研究证明了3d打印pac在解决日益严重的塑料污染挑战方面的潜力。
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来源期刊
Chemosphere
Chemosphere 环境科学-环境科学
CiteScore
15.80
自引率
8.00%
发文量
4975
审稿时长
3.4 months
期刊介绍: Chemosphere, being an international multidisciplinary journal, is dedicated to publishing original communications and review articles on chemicals in the environment. The scope covers a wide range of topics, including the identification, quantification, behavior, fate, toxicology, treatment, and remediation of chemicals in the bio-, hydro-, litho-, and atmosphere, ensuring the broad dissemination of research in this field.
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