Effect of powder morphology on tribological performance of HVAF-sprayed WC-CoCr coatings

IF 6.1 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS Surface & Coatings Technology Pub Date : 2025-06-01 Epub Date: 2025-03-26 DOI:10.1016/j.surfcoat.2025.132090
L. Bortolotti , G. Ruggiero , G. Bolelli , L. Lusvarghi , S. Morelli , S. Björklund , O. Lanz , S. Joshi
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Abstract

This study investigates the tribological behavior of WC-CoCr coatings deposited using High-Velocity Air Fuel (HVAF) thermal spraying. Three distinct types of feedstock powders were employed to examine the influence of powder morphology on coating performance: a dense, angular fused-and-crushed powder; a spherical, porous agglomerated-and-sintered powder, and a newly developed powder with intermediate features. All powders had analogous particle size distribution approximately in the range of 7–20 μm. Two coating thicknesses were deposited with each powder (50 μm and 150 μm), additionally aiming to verify the possibility of depositing thin hardmetal coatings. The coatings microstructure was characterized, their hardness and porosity were measured and their tribological properties were evaluated by means of ball-on-disk sliding tests and dry jet erosion tests at various impact angles.
The results demonstrated that powder morphology significantly affects deposition efficiency. The newly developed powder offers notable advantages, such as higher deposition efficiency, which accelerates the spraying process and boosts production productivity, along with reduced sensitivity to parameter variations. In fact, the newly developed powder exhibited more consistent deposition rates across varying process conditions. Coatings derived from the new manufacturing route powder also showed improved cohesion and hardness due to stronger interparticle bonding and peening effects. On the other hand, surface roughness was unaffected by the powder type, and the coatings produced from the three powders had comparable wear resistance under erosion and sliding conditions. Coating thickness, rather than powder morphology, appeared to play a greater role in determining wear performance. The thicker coatings demonstrated superior resistance under both test conditions, due to reduced substrate influence.
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粉末形貌对hvaf喷涂WC-CoCr涂层摩擦学性能的影响
研究了高速空气燃料(HVAF)热喷涂WC-CoCr涂层的摩擦学行为。采用三种不同类型的原料粉末来研究粉末形态对涂层性能的影响:一种致密的、棱角分明的熔合粉碎粉末;一种球形、多孔的烧结粉末,一种具有中间特性的新开发的粉末。所有粉末的粒径分布大致在7 ~ 20 μm之间。每种粉末沉积了两种厚度(50 μm和150 μm)的涂层,另外旨在验证沉积薄硬质合金涂层的可能性。通过球盘式滑动试验和不同冲击角下的干射流冲蚀试验,对涂层的显微组织进行了表征,测量了涂层的硬度和孔隙率,并对涂层的摩擦学性能进行了评价。结果表明,粉末形貌对沉积效率有显著影响。新开发的粉末具有显著的优点,例如更高的沉积效率,从而加快了喷涂过程并提高了生产效率,同时降低了对参数变化的敏感性。事实上,新开发的粉末在不同的工艺条件下表现出更一致的沉积速率。由于颗粒间结合和喷丸效果更强,新工艺粉末制成的涂层具有更好的凝聚力和硬度。另一方面,表面粗糙度不受粉末类型的影响,三种粉末制成的涂层在侵蚀和滑动条件下具有相当的耐磨性。涂层厚度,而不是粉末形态,似乎在决定磨损性能方面起着更大的作用。由于基材的影响减小,较厚的涂层在两种测试条件下都表现出优异的耐腐蚀性。
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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