Uranium separation from urine matrix using amidoximated crosslinked polyacrylonitrile adsorbent

IF 1.6 3区 化学 Q3 CHEMISTRY, ANALYTICAL Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-01-06 DOI:10.1007/s10967-024-09947-z
S. P. Prabhu, Amit Kanjilal, Sonali Gondane, P. D. Sawant, Awadhesh Kumar, Probal Chaudhury, M. S. Kulkarni
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Abstract

A rapid radiochemical separation method was developed for the assessment of uranium in urine using indigenously synthesised amidoximated crosslinked polyacrylonitrile (ACPAN) adsorbent. The synthesised adsorbent exhibited a high uranium adsorption capacity for urine samples conditioned at pH 2. The reusability of the ACPAN adsorbent was demonstrated by its stable adsorption capacity for ultra-trace levels of uranium over multiple cycles. The standardized method complied ANSI 13.30 radio bioassay performance criteria, validating the suitability of this novel technique for precise determination of uranium in urine. The method developed is rapid, sensitive, and can be applied for emergency bioassay of uranium in urine.

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偕胺肟化交联聚丙烯腈吸附剂从尿中分离铀
采用自制的偕胺肟化交联聚丙烯腈(ACPAN)吸附剂,建立了尿中铀的快速放射化学分离方法。合成的吸附剂对pH值为2的尿液样品具有较高的铀吸附能力。ACPAN吸附剂在多次循环中对超痕量铀具有稳定的吸附能力,证明了其可重复使用。标准化方法符合ANSI 13.30放射性生物测定性能标准,验证了这种新技术精确测定尿液中铀的适用性。该方法快速、灵敏,可用于尿中铀的应急生物测定。
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来源期刊
CiteScore
2.80
自引率
18.80%
发文量
504
审稿时长
2.2 months
期刊介绍: An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.
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