A novel dual optimization reagent enables ultra-bright and air-stable cesium copper iodine thin films

IF 4.2 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Optical Materials Pub Date : 2025-06-01 Epub Date: 2025-03-24 DOI:10.1016/j.optmat.2025.116984
Fushuai Li , Chuanhe Ma , Shu Li , Jinchun Jiang , Hailong Wang
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Abstract

Cesium copper iodine (CsCuI) perovskite LED (PeLED) possesses several advantages, including eco-friendly, high stability, abundant elements, and low cost. Improving the photoluminescent performance and stability of the CsCuI perovskite thin film, which serves as the emissive layer, is crucial for enhancing the overall PeLED performance. This paper reports a dual optimization strategy (DOS) that uses a novel mixed toluene (Tol) and oleic acid (OA) reagent. Tol acts as an antisolvent, and OA serves as a passivator. Experimental results show that the DOS increases crystal nucleation rate and mitigates film defects. The photoluminescence quantum yield (PLQY) of the Cs3Cu2I5 perovskite thin film prepared by DOS exceeds 90 %, and after 40 days of storing in air, the PLQY remains at the initial 88 %. This DOS, mixing antisolvent and passivator, also provides new ideas for improving other lead-free metal halide perovskites.
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一种新型的双优化试剂使超亮和空气稳定的铯铜碘薄膜
铯铜碘(ccui)钙钛矿LED (PeLED)具有环保、稳定性高、元素丰富、成本低等优点。提高作为发射层的ccui钙钛矿薄膜的光致发光性能和稳定性,对于提高PeLED的整体性能至关重要。本文报道了一种新型混合甲苯(Tol)和油酸(OA)试剂的双重优化策略。Tol作为抗溶剂,OA作为钝化剂。实验结果表明,DOS提高了晶体成核速率,减轻了薄膜缺陷。DOS法制备的Cs3Cu2I5钙钛矿薄膜的光致发光量子产率(PLQY)超过90%,在空气中贮存40天后,PLQY仍保持在初始的88%。这种混合了抗溶剂和钝化剂的DOS也为其他无铅金属卤化物钙钛矿的改进提供了新的思路。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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文献相关原料
公司名称
产品信息
麦克林
Oleic Acid
麦克林
Oleic Acid
阿拉丁
Copper Iodide
阿拉丁
Cesium Iodide
来源期刊
Optical Materials
Optical Materials 工程技术-材料科学:综合
CiteScore
6.60
自引率
12.80%
发文量
1265
审稿时长
38 days
期刊介绍: Optical Materials has an open access mirror journal Optical Materials: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. The purpose of Optical Materials is to provide a means of communication and technology transfer between researchers who are interested in materials for potential device applications. The journal publishes original papers and review articles on the design, synthesis, characterisation and applications of optical materials. OPTICAL MATERIALS focuses on: • Optical Properties of Material Systems; • The Materials Aspects of Optical Phenomena; • The Materials Aspects of Devices and Applications. Authors can submit separate research elements describing their data to Data in Brief and methods to Methods X.
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