Hydrogen entry into zinc-coated steel induced by atmospheric corrosion after local chloride deposition

IF 7.4 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Corrosion Science Pub Date : 2025-03-25 DOI:10.1016/j.corsci.2025.112885
Darja Rudomilova , Tomáš Prošek , Andreas Muhr , Gerald Luckeneder
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Abstract

Differences in hydrogen entry behaviour for bare steel, zinc-coated steel with artificial defects in the coating, and steel with intact zinc coating were studied using scanning Kelvin probe technique. Pit formation was a key factor in the hydrogen entry mechanism for bare steel specimens. The steel/zinc interface covered with zinc corrosion products is the principal area of hydrogen entry into sheets with artificial defects in zinc coating. Hydrogen uptake was also observed in intact zinc-coated steel. The presence of a long line defect in the zinc coating led to almost eight times higher hydrogen uptake compared to bare steel.
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局部氯化物沉积后大气腐蚀引起的氢进入镀锌钢
采用扫描开尔文探针技术研究了裸钢、人工缺陷镀锌钢和完整锌涂层钢的氢进入行为差异。坑的形成是裸钢试样氢进入机制的关键因素。锌腐蚀产物覆盖的钢/锌界面是氢进入含锌人为缺陷钢板的主要区域。在完整的镀锌钢中也观察到氢的吸收。锌涂层中存在的长线缺陷导致比裸钢高近8倍的氢气吸收率。
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来源期刊
Corrosion Science
Corrosion Science 工程技术-材料科学:综合
CiteScore
13.60
自引率
18.10%
发文量
763
审稿时长
46 days
期刊介绍: Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies. This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.
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