Feature of Nonlinear Electromagnetic Properties and Local Atomic Structure of Metals in Two Systems of Nanocomposites Cox(MgF2)100-x and (CoFeZr)x(MgF2)100-x.

IF 4.8 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY Nanomaterials Pub Date : 2025-03-19 DOI:10.3390/nano15060463
Evelina Pavlovna Domashevskaya, Sergey Alexandrovich Ivkov, Elena Alexandrovna Ganshina, Lyubov Vladimirovna Guda, Valeriy Grigoryevich Vlasenko, Alexander Victorovich Sitnikov
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Abstract

Based on modern concepts of the nonlinear percolation mechanisms of electrical and magnetic properties in granular metal-dielectric nanocomposites, the authors present for the first time a comparative analysis of their own results of a comprehensive study of nonlinear electromagnetic properties in two nanocomposite systems: metal-dielectric Cox(MgF2)100-x and alloy-dielectric (CoFeZr)x(MgF2)100-x, obtained by ion-beam sputtering of composite targets in a wide range of different compositions. For the first time, the features of the influence of atomic composition and structural-phase transitions on nonlinear magnetoresistive, magnetic, and magneto-optical properties in two systems are presented in comparison, one of which, Cox(MgF2)100-x, showed soft magnetic properties, and the second, (CoFeZr)x(MgF2)100-x, hard magnetic properties, during the transition from the superparamagnetic to the ferromagnetic state. Moreover, for the first time, the concentration dependences of the oscillating fine structure of XANES K-absorption edges of Co atoms in the first system and Co and Fe atoms in the second system are presented, which undergo changes at the percolation thresholds in each of the two systems and thus confirm the nonlinear nature of the electromagnetic properties changes in each of the two systems at the atomic level.

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纳米复合材料Cox(MgF2)100-x和(CoFeZr)x(MgF2)100-x体系中金属的非线性电磁特性和局部原子结构特征
基于颗粒状金属-介电纳米复合材料的非线性渗透机制的现代概念,作者首次对他们自己的两种纳米复合材料体系的非线性电磁特性的综合研究结果进行了比较分析:金属-介电Cox(MgF2)100-x和合金-介电(CoFeZr)x(MgF2)100-x,通过离子束溅射在广泛的不同成分的复合靶中获得。本文首次比较了两种体系中原子组成和结构相变对非线性磁阻、磁性和磁光性质的影响特征,其中Cox(MgF2)100-x在超顺磁性向铁磁性转变过程中表现为软磁性质,而(CoFeZr)x(MgF2)100-x表现为硬磁性质。此外,首次给出了第一种体系中Co原子和第二种体系中Co和Fe原子的XANES k吸收边振荡精细结构的浓度依赖性,它们在两种体系中都经历了渗透阈值的变化,从而在原子水平上证实了两种体系中电磁特性变化的非线性性质。
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来源期刊
Nanomaterials
Nanomaterials NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.50
自引率
9.40%
发文量
3841
审稿时长
14.22 days
期刊介绍: Nanomaterials (ISSN 2076-4991) is an international and interdisciplinary scholarly open access journal. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. Thus, theoretical and experimental articles will be accepted, along with articles that deal with the synthesis and use of nanomaterials. Articles that synthesize information from multiple fields, and which place discoveries within a broader context, will be preferred. There is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental or methodical details, or both, must be provided for research articles. Computed data or files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Nanomaterials is dedicated to a high scientific standard. All manuscripts undergo a rigorous reviewing process and decisions are based on the recommendations of independent reviewers.
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