Highly sensitive and full range laser methane gas detector based on automatic wavelength-switching algorithm

IF 3.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL Sensors and Actuators B: Chemical Pub Date : 2025-08-15 Epub Date: 2025-04-01 DOI:10.1016/j.snb.2025.137699
Haiyong Chen , Hua-Yao Li , Hongjun Ren , Haichao Wang , Peng Chen , Dongge Guo , Huajie Zhang , Mengchao Yan , Shunjie Ran , Tianjun Shang , Huan Liu
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Abstract

To address the challenge of achieving both high sensitivity and a wide dynamic range in methane (CH4) leakage detection for municipal gas and petrochemical industries, this study presents a highly sensitive, full-range CH4 detector based on tunable diode laser absorption spectroscopy (TDLAS). The detector integrates direct absorption spectroscopy (DAS) and wavelength modulation spectroscopy (WMS) techniques. An automatic wavelength-switching algorithm is implemented to alternate between strong and weak absorption lines via the DAS method, while the WMS technique is employed for accurate gas concentration measurement. The developed CH4 gas detector demonstrates a detection limit as low as 0.169 ppm and a dynamic range extending up to 100 % volume concentration, with a linear regression coefficient (R²) of 0.9996 across the full range. Compared to existing detectors, this approach achieves substantial advancements in sensor size, effective optical path length, and detection sensitivity, fulfilling the requirements for portable, high-performance gas detection equipment.
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基于自动波长切换算法的高灵敏度全量程激光甲烷气体检测仪
为了解决城市燃气和石化行业甲烷(CH4)泄漏检测的高灵敏度和宽动态范围的挑战,本研究提出了一种基于可调谐二极管激光吸收光谱(TDLAS)的高灵敏度、全量程CH4探测器。该探测器集成了直接吸收光谱(DAS)和波长调制光谱(WMS)技术。通过DAS法实现了波长自动切换算法,实现了强吸收线和弱吸收线的交替,同时采用WMS技术实现了气体浓度的精确测量。所研制的CH4气体检测仪检出限低至0.169 ppm,动态范围扩展至100%体积浓度,全范围线性回归系数(R²)为0.9996。与现有的探测器相比,这种方法在传感器尺寸、有效光程长度和检测灵敏度方面取得了实质性的进步,满足了便携式高性能气体检测设备的要求。
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来源期刊
Sensors and Actuators B: Chemical
Sensors and Actuators B: Chemical 工程技术-电化学
CiteScore
14.60
自引率
11.90%
发文量
1776
审稿时长
3.2 months
期刊介绍: Sensors & Actuators, B: Chemical is an international journal focused on the research and development of chemical transducers. It covers chemical sensors and biosensors, chemical actuators, and analytical microsystems. The journal is interdisciplinary, aiming to publish original works showcasing substantial advancements beyond the current state of the art in these fields, with practical applicability to solving meaningful analytical problems. Review articles are accepted by invitation from an Editor of the journal.
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