An airborne CH4 sensor with temperature compensation based on a miniature optical structure for natural gas pipeline leakage analysis

Guolin Li, Haoran Yuan, Yingjie Zhao, Guangzhao Cui, Ruixiang Sun, Longju Li, Jianyu Gu, Wenxuan Zhao, Jinxu Yang
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Abstract

Pipeline transport plays an important role in the exploration and transmission of natural gas. An airborne near-infrared (NIR) methane (CH4) sensor has been developed to analyze CH4 leakage in the pipeline transport process based on the tunable diode laser absorption spectroscopy combined with wavelength modulation spectroscopy (WMS-TDLAS) technology relying on the high efficiency and convenience of unmanned aerial vehicles (UAVs). A laser diode in the form of an ultra-compact 8-pin package with a center wavelength of 1653.7 nm and an independently-designed miniature optical structure with an optical path length of 36 cm are adopted, which greatly reduces the size of the sensor. In order to improve the measurement accuracy, a temperature compensation link is designed to minimize the influence of temperature changes on the measured value. The original second harmonic signal is denoised by the variational mode decomposition algorithm optimized by Genghis Khan shark optimizer algorithm (GKSO-VMD), and the Bi-directional long short-term memory GKSO-BiLSTM algorithm is used for CH4 concentration inversion. The measured and real concentration values of the sensor are closely related, with a correlation coefficient (R2) of 0.9996. The response time experiment demonstrates that the response time is approximately 6 s. The great stability of the sensor is confirmed by the long-term stability experiment. According to the Allan–Werle deviation, it is estimated that the sensor has a limit of detection (LoD) 613 ppb with an integration time of 230 s. Therefore, an effective analysis method is proposed for CH4 leakage analysis during natural gas pipeline transport.

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基于微型光学结构的气载甲烷温度补偿传感器用于天然气管道泄漏分析
管道运输在天然气勘探和输送中起着重要的作用。基于可调谐二极管激光吸收光谱结合波长调制光谱(WMS-TDLAS)技术,利用无人机的高效率和便捷性,研制了一种机载近红外甲烷(CH4)传感器,用于分析管道输送过程中的CH4泄漏。采用超紧凑8针封装形式的激光二极管,中心波长为1653.7 nm,采用自主设计的光路长度为36 cm的微型光学结构,大大减小了传感器的尺寸。为了提高测量精度,设计了温度补偿环节,使温度变化对测量值的影响降到最低。原始二次谐波信号采用成吉思汗鲨鱼优化算法(GKSO-VMD)优化的变分模态分解算法去噪,CH4浓度反演采用双向长短期记忆GKSO-BiLSTM算法。传感器的实测值与浓度值密切相关,相关系数(R2)为0.9996。响应时间实验表明,响应时间约为6 s。长期稳定性实验证实了该传感器的高稳定性。根据Allan-Werle偏差,估计传感器的检测极限(LoD)为613 ppb,积分时间为230 s。为天然气管道输送过程中CH4泄漏分析提供了一种有效的分析方法。
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来源期刊
CiteScore
8.40
自引率
11.40%
发文量
1364
审稿时长
40 days
期刊介绍: Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy (SAA) is an interdisciplinary journal which spans from basic to applied aspects of optical spectroscopy in chemistry, medicine, biology, and materials science. The journal publishes original scientific papers that feature high-quality spectroscopic data and analysis. From the broad range of optical spectroscopies, the emphasis is on electronic, vibrational or rotational spectra of molecules, rather than on spectroscopy based on magnetic moments. Criteria for publication in SAA are novelty, uniqueness, and outstanding quality. Routine applications of spectroscopic techniques and computational methods are not appropriate. Topics of particular interest of Spectrochimica Acta Part A include, but are not limited to: Spectroscopy and dynamics of bioanalytical, biomedical, environmental, and atmospheric sciences, Novel experimental techniques or instrumentation for molecular spectroscopy, Novel theoretical and computational methods, Novel applications in photochemistry and photobiology, Novel interpretational approaches as well as advances in data analysis based on electronic or vibrational spectroscopy.
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