An open hollow polyoxovanadate cage based on {Nb(V5)} pentagons with size-selective encapsulation properties†

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2025-03-20 Epub Date: 2025-03-25 DOI:10.1039/d5cc01376c
Renbo Fang , Di Zhang , Jing Dong , Yeqin Feng , Chengpeng Liu , Liaoyuan Yao , Yingnan Chi , Changwen Hu
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Abstract

An open hollow polyoxovanadate (POV) cage, , has been successfully constructed using {Nb(V5)} pentagons as building blocks. The POV cage features a crown-ether-like {V4P4O8} opening that can selectively coordinate with Cs+ ions. Additionally, it has a hollow cavity that acts as a molecular container to accommodate size-appropriate organic molecules.

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基于{Nb(V5)}五边形的开放式空心聚钒氧酸笼具有尺寸选择性封装性能。
以{Nb(V5)}五边形为材料,成功构建了开放式空心聚钒氧酸盐笼(V14Nb2P8)。POV笼具有冠状醚状的{V4P4O8}开口,可以选择性地与Cs+离子配位。此外,它有一个空心腔,作为分子容器容纳大小合适的有机分子。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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