Co-polarized electret fibers tailored by in-situ microphase separation for high-performance oil mist filter

IF 4.5 2区 化学 Q2 POLYMER SCIENCE Polymer Pub Date : 2025-04-02 DOI:10.1016/j.polymer.2025.128345
Qinghan Du , Juhui Yin , Haoxin Liu , Shuming Zhang , Yuyao Li
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Abstract

Oily particulate matter has emerged as a critical environmental and occupational hazard, significantly posing risks to both worker health and industrial machinery. Although glass fiber nonwovens are widely used to tackle this issue, they usually show inadequate efficiency while filtering small oil mists limited by their micro-sized large fiber diameter and single mechanical filtering mechanism. Herein, electret nanofibrous membranes with co-polarized property are in situ synthesized via electrospinning, which derives from the precisely tailoring of dual-polymers microphase separation along with the charge injection. Benefitting from the enhanced co-polarized effect of two polymers with completely different polarization, the electret performance of composite membranes can increase by 238 % compared to single-polymer membranes. What's more, the resulting membranes exhibited a dense, porous structure, achieving an oil mist filtration efficiency of 98.77 % and an air resistance as low as 38.92 Pa. This new strategy offers a novel solution for the design and development of next-generation oil mist filtration materials.

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用于高性能油雾过滤器的原位微相分离共极化驻极体纤维
油性颗粒物质已成为一种严重的环境和职业危害,对工人健康和工业机械构成重大风险。虽然玻璃纤维非织造布被广泛用于解决这一问题,但由于玻璃纤维非织造布的纤维直径小、机械过滤机制单一,过滤小油雾的效率往往不高。本文通过静电纺丝的方法原位合成了具有共极化特性的驻极体纳米纤维膜,该方法源于双聚合物微相分离与电荷注入的精确剪裁。得益于两种极化完全不同的聚合物增强的共极化效应,复合膜的驻极体性能比单聚合物膜提高了238%。此外,制备的膜具有致密的多孔结构,油雾过滤效率为98.77%,空气阻力低至38.92 Pa。这种新策略为下一代油雾过滤材料的设计和开发提供了一种新颖的解决方案。
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来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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