Rapid unidirectional growth of electronic micro-intermetallic interconnects with prismatic grains

IF 5.5 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Materials Characterization Pub Date : 2025-03-28 DOI:10.1016/j.matchar.2025.114958
Ye Tian , Rubin Yan , Yuejun Li , Zhongyu Liu , Waqas Saeed , Xing Chen , Wei Liu , Zhiwen Chen
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Abstract

As conventional solder interconnects continuously downsize to less than 20 μm in three-dimensional integrated circuits, the rapid fabrication of reliable micro-intermetallic interconnects in chip stacking has become a critical concern. A temperature gradient (TG) process was investigated to fabricate micro-intermetallic interconnect. The results showed that the resulting interconnect consists of single prismatic Cu6Sn5 grains surrounded by Sn solder within only 7 min, which is nearly 7 times faster than the conventional SLID process. The contained Cu6Sn5 grains and Sn grains exhibited highly preferred orientations, indicating a unidirectional formation of the interconnect and thereby achieving controllable properties. The mechanisms of this unidirectional growth were elucidated and experimentally verified. The properties were examined to demonstrate desirable features including high mechanical strength and low electronic resistance. Furthermore, the soft Sn solder surrounding Cu6Sn5 grains may enhance the interconnects resistance against brittle fracture under mechanical shock conditions. The TG process and resulting oriented micro-intermetallic interconnects offer a promising solution for next-generation chip stacking.
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具有棱柱状晶粒的电子微金属间互连材料的快速单向生长
随着三维集成电路中传统焊料互连的尺寸不断缩小到20 μm以下,在芯片堆叠中快速制造可靠的微型金属间互连已成为一个关键问题。研究了用温度梯度法制备金属间微细互连的工艺。结果表明,该工艺在7 min内完成了由锡焊料包围的Cu6Sn5晶粒组成的单棱柱形互连,比传统的滑移工艺快了近7倍。所含Cu6Sn5晶粒和Sn晶粒表现出高度的择优取向,表明相互连接是单向形成的,从而实现了性能的可控。对这种单向生长的机理进行了阐述和实验验证。性能测试证明了理想的特点,包括高机械强度和低电阻。此外,Cu6Sn5晶粒周围的软锡焊料可以增强互连线在机械冲击条件下抗脆性断裂的能力。TG工艺和由此产生的定向微金属间互连为下一代芯片堆叠提供了一个有前途的解决方案。
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来源期刊
Materials Characterization
Materials Characterization 工程技术-材料科学:表征与测试
CiteScore
7.60
自引率
8.50%
发文量
746
审稿时长
36 days
期刊介绍: Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials. The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal. The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include: Metals & Alloys Ceramics Nanomaterials Biomedical materials Optical materials Composites Natural Materials.
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