Synthesis and characterization of CuO nano-leaves prepared by the simple hot-water-vapor method, the influence of oxidation time duration for solar cell applications

IF 4 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Optical and Quantum Electronics Pub Date : 2025-04-03 DOI:10.1007/s11082-025-08165-5
Monireh Jafari, Hosein Eshghi
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Abstract

The simple hot-water-vapor (HWV) method was used to make the copper oxide nanostructures on Cu sheets for this study. The effects of oxidation times of 8, 16, and 24 h were investigated for use in solar cells. The samples were characterized using FESEM, EDX, XRD, Raman, and DRS measurements. It is found that with increasing the synthesis time duration: (1) the FESEM images showed a combination of cubic and nano-leaves gradually turned into compact nano-leaves; (2) EDX, XRD, and Raman analyses on the samples showed that the layers that were grown got closer to the CuO phase’s elemental ratio, and the crystallite size (D) grew from 17.55 to 34.66 nm; (3) It was found that the CuO phase-related band gap decreased from 1.62 to 1.43 eV as the crystallinity and phase purity of the samples improved, which could be a beneficial property for solar cell applications.

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用简单的热水-蒸汽法制备的纳米氧化铜叶片的合成与表征,氧化时间长短对太阳能电池应用的影响
本研究采用简单的热水蒸气法在铜片上制备氧化铜纳米结构。研究了8、16和24 h的氧化时间对太阳能电池的影响。采用FESEM、EDX、XRD、Raman和DRS等方法对样品进行了表征。研究发现,随着合成时间的延长:(1)FESEM图像显示立方体和纳米叶片的组合逐渐变为致密的纳米叶片;(2)对样品的EDX、XRD和Raman分析表明,生长的层越来越接近CuO相的元素比,晶粒尺寸(D)从17.55 nm增大到34.66 nm;(3)随着样品结晶度和相纯度的提高,CuO相相关带隙从1.62 eV减小到1.43 eV,这对太阳能电池的应用是有利的。
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来源期刊
Optical and Quantum Electronics
Optical and Quantum Electronics 工程技术-工程:电子与电气
CiteScore
4.60
自引率
20.00%
发文量
810
审稿时长
3.8 months
期刊介绍: Optical and Quantum Electronics provides an international forum for the publication of original research papers, tutorial reviews and letters in such fields as optical physics, optical engineering and optoelectronics. Special issues are published on topics of current interest. Optical and Quantum Electronics is published monthly. It is concerned with the technology and physics of optical systems, components and devices, i.e., with topics such as: optical fibres; semiconductor lasers and LEDs; light detection and imaging devices; nanophotonics; photonic integration and optoelectronic integrated circuits; silicon photonics; displays; optical communications from devices to systems; materials for photonics (e.g. semiconductors, glasses, graphene); the physics and simulation of optical devices and systems; nanotechnologies in photonics (including engineered nano-structures such as photonic crystals, sub-wavelength photonic structures, metamaterials, and plasmonics); advanced quantum and optoelectronic applications (e.g. quantum computing, memory and communications, quantum sensing and quantum dots); photonic sensors and bio-sensors; Terahertz phenomena; non-linear optics and ultrafast phenomena; green photonics.
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