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Exploring random laser characteristics in core@ shell nano-scatter centers: trends and opportunities 探索核@壳纳米散射中心的随机激光特性:趋势与机遇
IF 3.3 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-24 DOI: 10.1007/s11082-024-06881-y
Noor al-huda A. Abass, Muslim F. Jawad, Adawiya J. Haider, Bakr A. Taha

Concise review explores random lasers, utilizing a scattering medium for optical feedback instead of this the conventional optical cavity found in traditional lasers. Random laser generation relies on gain and dispersion for optical feedback and amplification. Among the myriad of complex nanostructures, surface-based nanomaterials are gaining attention. The materials take the form of core@ shell nanostructures, combining individual properties while maintaining distinct characteristics. In the realm of intelligence research, there is a significant emphasis on synthesizing core@ shell nanoparticles (NPS). Noble metals such as Au, Ag, Pt, and Pd serve as core materials, while metal oxide semiconductors like TiO2, SnO2, and Cu2O act as shell materials. This recent development has sparked considerable interest. The unique arrangement and function of the core and shell lead to diverse applications, including comprehensive photovoltaic systems, color-coded solar cells, and more. Furthermore, these core@ shell nanostructures find applications in random lasers, influencing fields such as medicine and technology. The implementation of random lasers extends to medical imaging devices, displays, sensors, and distinctive sign technologies. As researchers continue to explore the intricate characteristics of core@ shell nanostructures, new trends and opportunities are likely to emerge, promising breakthroughs in various scientific and technological domains.

简明综述探讨了随机激光器,它利用散射介质进行光反馈,而不是传统激光器中的传统光腔。随机激光的产生依靠增益和色散进行光反馈和放大。在无数复杂的纳米结构中,基于表面的纳米材料越来越受到关注。这些材料采用 "芯@壳 "纳米结构的形式,在保持独特特性的同时还结合了各自的特性。在情报研究领域,核@壳纳米粒子(NPS)的合成受到极大重视。金、银、铂和钯等贵金属是核心材料,而 TiO2、SnO2 和 Cu2O 等金属氧化物半导体则是外壳材料。这一最新进展引起了人们的极大兴趣。核心和外壳的独特排列和功能带来了多种多样的应用,包括综合光伏系统、彩色编码太阳能电池等。此外,这些 "芯@壳 "纳米结构还可应用于随机激光器,对医学和技术等领域产生影响。随机激光的应用扩展到医疗成像设备、显示器、传感器和独特的标志技术。随着研究人员继续探索芯@壳纳米结构的复杂特性,新的趋势和机遇可能会出现,有望在各个科学和技术领域取得突破。
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引用次数: 0
Exploring the Lie symmetries, conservation laws, bifurcation analysis and dynamical waveform patterns of diverse exact solution to the Klein–Gordan equation 探索克莱因-戈尔丹方程多种精确解的李对称性、守恒定律、分岔分析和动态波形模式
IF 3.3 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-23 DOI: 10.1007/s11082-024-07814-5
Tariq Mahmood, Ghadah Alhawael, Sonia Akram, Mati ur Rahman

This paper presents a comprehensive analysis of the ((1+1))-dimensional Klein-Gordan equation which plays a significant role in various areas of theoretical and applied physics. The main focus of this research centers on several key areas. First, infinitesimal generators of symmetries were found by Lie symmetry invariance analysis. Then, using the adjoint representation, an ideal system was created based on the found Lie vectors. Secondly, by utilizing the analytical approach, namely the modified Sardar sub equation method, we systematically derive various novel soliton solution in the form of dark, bright, periodic, singular, combo, hyperbolic as well as mixed trigonometric. Finally, bifurcation analysis is performed at the system’s fixed points, revealing chaotic behavior when an external force is introduced into the dynamic system. To identify the chaotic characteristics, a range of tools, such as 3D and 2D phase plots, time series, Lyapunov exponents, and multistability analysis, are utilized. Additionally, the sensitivity analysis of the model is examined under different initial conditions. These results enhance the understanding of nonlinear wave phenomena in mathematical physics and hold potential applications across numerous scientific disciplines.

本文全面分析了((1+1))维克莱因-哥尔登方程,该方程在理论物理和应用物理的各个领域发挥着重要作用。这项研究的重点集中在几个关键领域。首先,通过李对称不变性分析找到了对称性的无穷小发生器。然后,利用邻接表示法,根据所发现的 Lie 向量创建了一个理想系统。其次,利用分析方法,即改进的萨达尔子方程法,我们系统地推导出了暗解、亮解、周期解、奇异解、组合解、双曲解以及混合三角解等各种新颖的孤子解。最后,我们在系统的固定点进行了分岔分析,揭示了在动态系统中引入外力时的混沌行为。为了识别混沌特性,我们使用了一系列工具,如三维和二维相位图、时间序列、Lyapunov 指数和多稳定性分析。此外,还研究了模型在不同初始条件下的敏感性分析。这些成果加深了人们对数学物理中非线性波现象的理解,并在众多科学学科中具有潜在的应用价值。
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引用次数: 0
Determination and understanding of the structural electronic dynamic elastic and optic properties of Li2GaSb and Li3Sb by density functional theory 通过密度泛函理论确定和理解 Li2GaSb 和 Li3Sb 的结构电子动态弹性和光学特性
IF 3.3 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-23 DOI: 10.1007/s11082-024-07391-7
Sinem Erden Gulebaglan, Emel Kilit Dogan

In this work, the structural, electronic, elastic, optical and dynamic properties of Li3Sb and Li2GaSb crystal structures were researched by using the density functional theory applied in Abinit and Quantum Espresso package programs. All calculations in both programs were performed using the Generalized Gradient Approximation as an exchange–correlation function in Kohn–Sham equations. When the structural properties of the crystals were examined, they were found to be in good agreement with other theoretical results. As a result of the calculations related to the electronic properties, it was determined that the Li3Sb crystal exhibited semiconducting properties and the Li2GaSb crystal exhibited metallic properties. Then, focusing on the dynamic properties of Li3Sb and Li2GaSb crystals, it was concluded that both crystals are dynamically stable. From the calculations made, it was concluded that the stable state did not deteriorate when pressure was applied to the Li3Sb crystal, but the stable state deteriorated when pressure was applied to the Li2GaSb crystal from 528 kbar pressure. In addition, the calculations showed that the thermal conductivity of Li3Sb is higher than that of Li2GaSb. By calculating the elastic properties, it was found that Li3Sb is a brittle material while Li2GaSb is an elastic material. Finally, based on the semiconductor properties of the Li3Sb crystal, its optical properties were investigated.

在这项研究中,我们使用 Abinit 和 Quantum Espresso 软件包程序中的密度泛函理论研究了 Li3Sb 和 Li2GaSb 晶体结构的结构、电子、弹性、光学和动态特性。这两个程序中的所有计算均使用广义梯度近似法作为 Kohn-Sham 方程中的交换相关函数。在对晶体的结构特性进行检验时,发现它们与其他理论结果十分吻合。通过与电子特性相关的计算,确定 Li3Sb 晶体具有半导体特性,而 Li2GaSb 晶体具有金属特性。然后,重点研究了 Li3Sb 和 Li2GaSb 晶体的动态特性,得出的结论是这两种晶体都具有动态稳定性。通过计算得出的结论是,当对 Li3Sb 晶体施加压力时,稳定状态不会恶化,但当对 Li2GaSb 晶体施加 528 kbar 压力时,稳定状态会恶化。此外,计算表明 Li3Sb 的热导率高于 Li2GaSb。通过计算弹性特性,发现 Li3Sb 是一种脆性材料,而 Li2GaSb 是一种弹性材料。最后,根据 Li3Sb 晶体的半导体特性,对其光学特性进行了研究。
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引用次数: 0
Intensity features of the general model vortex higher‑order cosh‑Gaussian beam in free space and gradient-index media 自由空间和梯度指数介质中一般模型涡旋高阶 cosh-Gaussian 光束的强度特征
IF 3.3 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-23 DOI: 10.1007/s11082-024-07818-1
Ahmed Abdulrab Ali Ebrahim, Faroq Saad, Abdelmajid Belafhal

In the framework of the generalized Huygens–Fresnel diffraction integral and paraxial approximation theory, the propagation features of the general model vortex higher-order cosh-Gaussian beam (GMvHchGB) in a free space (FS) and a gradient-index medium (GIM) are studied. The analytical formulas of the GMvHchGB propagating through the considered media are derived. According to the derived formulas, some numerical examples of the normalized intensity distributions and corresponding phase structure of the GMvHchGB in both FS and GIM are performed under different parameter conditions during propagation setups. The obtained results show that the beam with higher decentered parameters, the GMvHchGB propagating in FS case cannot maintain its initial shape during the propagation process, whereas the beam propagation in the GIM case will keep the original shape unchanged with a repeated self-focusing along propagation distances. Finally, the numerical results of both intensity and phase distributions demonstrated that the beam order N significantly influences the vortex property of the beam, which enhances the clear importance of the current work.

在广义惠更斯-菲涅尔衍射积分和准轴近似理论的框架内,研究了一般模型涡旋高阶余弦高斯光束(GMvHchGB)在自由空间(FS)和梯度指数介质(GIM)中的传播特征。推导了在所考虑介质中传播的 GMvHchGB 的分析公式。根据推导出的公式,在传播设置过程中的不同参数条件下,对自由空间和梯度指数介质中 GMvHchGB 的归一化强度分布和相应的相位结构进行了一些数值示例。结果表明,在 FS 条件下传播的 GMvHchGB 光束具有较高的去中心参数,在传播过程中无法保持其初始形状,而在 GIM 条件下传播的光束在传播距离上反复自聚焦后将保持原有形状不变。最后,强度和相位分布的数值结果表明,光束阶数 N 对光束的涡旋特性有显著影响,这增强了当前工作的明显重要性。
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引用次数: 0
A metamaterial backed hybrid fractal microstrip patch antenna, integrated with an EM lens for non-invasive hyperthermia of skin cancer 集成了电磁透镜的超材料混合分形微带贴片天线,用于对皮肤癌进行无创热疗
IF 3.3 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-23 DOI: 10.1007/s11082-024-07746-0
Komalpreet Kaur, Amanpreet Kaur, Arnab Pattanayak, Diptiman Choudhury

The manuscript presents the design and development of a Microwave Hyperthermia (MHT) applicator integrated with an Electromagnetic (EM) lens. The purpose of the proposed MHT applicator is to provide non-invasive microwave hyperthermia treatment for skin cancer. The proposed MHT applicator comprises of an EM lens (133.75 × 133.75 mm3) placed ahead of a Hybrid Fractal Microstrip Patch Antenna (HFMA) (30 × 26 × 1.645 mm3), backed by a Meshedgrid-shaped Artificial magnetic Conductor (AMC) (48 × 48 × 3.27 mm3) reflector at an optimal distance of 16 mm The prototype of the HFMA is fabricated on a Rogers (RT5880) substrate and offers an impedance BW of 278 MHz, for a frequency from 2.316 to 2.594 GHz. To improve the front-to-back ratio (FBR) of the proposed HFMA, an EM lens that reduces the beam width and concentrated the energy in the desired direction is integrated with the AMC-backed HFMA. The final MHT applicator configuration provides a 3 dB beam width of 49.6° and a gain of 7.35 dBi at 2.45 GHz. The testing and validation  of the proposed MHT applicator is carried out in a simulation environment using Computer Simulation Technology (CST) Multiphysics for thermal analysis to check the temperature rise in the phantom. An in-vitro sample of skin phantom with a tumor is prepared using chemicals mimicking skin properties is exposed to the EM radiations emitted by the proposed HT applicator excited using a RF signal generator and power amplifier. the temperature rise in the phantom is recorded using optical temperature measurement probe. A temperature rise in the cancer-affected area up to 44 °C (Effective Temperature Area (ETA) 36 × 20 mm2) is observed in the simulation environment for an exposure time of approx. 45 min and in the measurement environment after a span of 25 minuites. A reported Specific Absorption Rate (SAR) value of 10 W/Kg shows that the proposed MHT applicator is safe for human exposure, and also reduces hot spots by enhancing the focus with controlled temperature, thus making the proposed applicator safe for human exposure.

该手稿介绍了一种与电磁(EM)透镜集成的微波热疗(MHT)治疗仪的设计和开发。拟议的微波热疗治疗仪旨在对皮肤癌进行无创微波热疗。拟议的 MHT 治疗仪包括一个电磁透镜(133.75 × 133.75 mm3),放置在混合分形微带贴片天线(HFMA)(30 × 26 × 1.645 mm3)的前面,后面是一个网格状人工磁导体(AMC)(48 × 48 × 3.HFMA 原型是在罗杰斯(Rogers)(RT5880)基板上制造的,阻抗 BW 为 278 MHz,频率为 2.316 至 2.594 GHz。为了提高拟议 HFMA 的前后比 (FBR),在 AMC 支持的 HFMA 中集成了一个电磁透镜,可减小波束宽度并将能量集中到所需方向。最终的 MHT 应用器配置在 2.45 GHz 频率下可提供 49.6° 的 3 dB 波束宽度和 7.35 dBi 的增益。在模拟环境中使用计算机仿真技术 (CST) Multiphysics 进行热分析,以检查模型中的温升,从而对拟议的 MHT 贴片机进行测试和验证。使用模拟皮肤特性的化学物质制备了带有肿瘤的体外皮肤模型样本,将其暴露在由使用射频信号发生器和功率放大器激发的拟议高温热疗涂抹器发出的电磁辐射下。在模拟环境中,暴露时间约为 45 分钟,而在测量环境中,暴露时间为 25 分钟,受癌症影响区域的温升最高可达 44 °C(有效温度区域 (ETA) 36 × 20 mm2)。所报告的比吸收率(SAR)值为 10 W/Kg,这表明拟议的 MHT 喷涂器对人体接触是安全的,而且还通过在温度受控的情况下增强聚焦来减少热点,从而使拟议的喷涂器对人体接触是安全的。
{"title":"A metamaterial backed hybrid fractal microstrip patch antenna, integrated with an EM lens for non-invasive hyperthermia of skin cancer","authors":"Komalpreet Kaur,&nbsp;Amanpreet Kaur,&nbsp;Arnab Pattanayak,&nbsp;Diptiman Choudhury","doi":"10.1007/s11082-024-07746-0","DOIUrl":"10.1007/s11082-024-07746-0","url":null,"abstract":"<div><p>The manuscript presents the design and development of a Microwave Hyperthermia (MHT) applicator integrated with an Electromagnetic (EM) lens. The purpose of the proposed MHT applicator is to provide non-invasive microwave hyperthermia treatment for skin cancer. The proposed MHT applicator comprises of an EM lens (133.75 × 133.75 mm<sup>3</sup>) placed ahead of a Hybrid Fractal Microstrip Patch Antenna (HFMA) (30 × 26 × 1.645 mm<sup>3</sup>), backed by a Meshedgrid-shaped Artificial magnetic Conductor (AMC) (48 × 48 × 3.27 mm<sup>3</sup>) reflector at an optimal distance of 16 mm The prototype of the HFMA is fabricated on a Rogers (RT5880) substrate and offers an impedance BW of 278 MHz, for a frequency from 2.316 to 2.594 GHz. To improve the front-to-back ratio (FBR) of the proposed HFMA, an EM lens that reduces the beam width and concentrated the energy in the desired direction is integrated with the AMC-backed HFMA. The final MHT applicator configuration provides a 3 dB beam width of 49.6° and a gain of 7.35 dBi at 2.45 GHz. The testing and validation  of the proposed MHT applicator is carried out in a simulation environment using Computer Simulation Technology (CST) Multiphysics for thermal analysis to check the temperature rise in the phantom. An in-vitro sample of skin phantom with a tumor is prepared using chemicals mimicking skin properties is exposed to the EM radiations emitted by the proposed HT applicator excited using a RF signal generator and power amplifier. the temperature rise in the phantom is recorded using optical temperature measurement probe. A temperature rise in the cancer-affected area up to 44 °C (Effective Temperature Area (ETA) 36 × 20 mm<sup>2</sup>) is observed in the simulation environment for an exposure time of approx. 45 min and in the measurement environment after a span of 25 minuites. A reported Specific Absorption Rate (SAR) value of 10 W/Kg shows that the proposed MHT applicator is safe for human exposure, and also reduces hot spots by enhancing the focus with controlled temperature, thus making the proposed applicator safe for human exposure.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"56 12","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142692005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, optical, surface topographical and electrical properties of transparent vanadium doped ZnO absorbing layer for photovoltaic application 用于光伏应用的透明掺钒氧化锌吸收层的结构、光学、表面形貌和电学特性
IF 3.3 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-23 DOI: 10.1007/s11082-024-07185-x
Apoorva Katoch, Navneet Kaur, Iqbal Singh, Aman Mahajan, Balraj Singh, Vandana Shinde, Raminder Kaur

In the present investigation, vanadium-doped zinc oxide (V: ZnO) thin films were synthesized by the sol-gel dip-coating technique by varying the percentage of V. Raman spectroscopy was used for structural conformation, showing the making of an impurity phase on increasing the V doping whereas, SEM analysis revealed that increasing the vanadium (V) concentration surface gets smoothen. The V incorporation into the ZnO crystal lattice was confirmed by the EDS analysis. The 3-D surface topography and stereometric analysis show the 3-D surface texture parameters that affect the optical and electrical features of the material. The results from experimental measurements suggest that V: ZnO thin films prepared at 3% V had the most suitable surface in terms of roughness, texture, and waviness. UV analysis showed a decrease in Eg value with an increase in the doping percentage, the optical parameters such as absorption and transmission (%) were also analyzed. The electrical properties were studied using I-V measurements from which resistivity for doped ZnO films was found to significantly decrease and increase its current densities. In photovoltaic characteristic evaluation, the efficiency (η) was attributed to variation in the value of Jsc. The C-3 coated PV cells had superior JSC at 36.70 mA/cm2, resulting an increased overall efficiency without changing the open-circuit voltage or fill factor. Thus, 3% doping concentration has a favourable influence on PV cell performance, indicating a possible path for improving energy conversion efficiencyby ~ 11.76% with better stability. This material can be proven as a good coating-absorbing layer for PV cells.

本研究采用溶胶-凝胶浸涂技术合成了掺钒氧化锌(V:ZnO)薄膜,并改变了掺钒的比例。拉曼光谱用于结构构象分析,显示掺钒量增加时会产生杂质相,而扫描电镜分析则显示钒(V)浓度增加时表面会变得更平滑。EDS 分析证实了氧化锌晶格中掺入了钒。三维表面形貌和立体计量分析显示了影响材料光学和电学特性的三维表面纹理参数。实验测量结果表明,以 3% V 制备的氧化锌薄膜在粗糙度、纹理和波浪度方面具有最合适的表面。紫外线分析表明 Eg 值随着掺杂百分比的增加而降低,同时还分析了吸收和透射率(%)等光学参数。通过 I-V 测量研究了电学特性,发现掺杂氧化锌薄膜的电阻率显著降低,电流密度显著增加。在光伏特性评估中,效率(η)与 Jsc 值的变化有关。C-3 涂层光伏电池的 JSC 值为 36.70 mA/cm2,具有更高的性能,从而在不改变开路电压或填充因子的情况下提高了总效率。因此,3% 的掺杂浓度对光伏电池的性能产生了有利影响,为以更高的稳定性将能量转换效率提高约 11.76% 指明了可能的途径。这种材料可作为光伏电池的良好涂层吸收层。
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引用次数: 0
Multi-wavelength actively Q-switched random fiber laser based on EOM and a real-time configurable filter 基于 EOM 和实时可配置滤波器的多波长主动调 Q 随机光纤激光器
IF 3.3 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-23 DOI: 10.1007/s11082-024-07407-2
Rupeng Li, Zhanzhi Liu, Honggang Pan, Hongli Dai, Chunqi Chen, Zihong Zhao

A multi-wavelength actively Q-switched random fiber laser based on real-time configurable Waveshaper and electro-optic modulator is proposed and experimentally demonstrated. The random feedback of the laser is provided by Rayleigh scattering generated by the single-mode fiber. The Waveshaper not only acts as a multi-channel filter, but also introduces wavelength-dependent losses in the laser cavity, which can suppress the mode competition caused by uniform broadening of the erbium-doped fiber and the power imbalance caused by Rayleigh scattering. Additional dispersion, group delay, phase and other parameters can be introduced through Waveshaper, and then the influence of additional quantities such as dispersion on actively Q-switched random fiber laser is studied. In the experiment, when the additional dispersion changes within -200 ~ 200 ps/nm, the pulse width of actively Q-switched can change between 1.01 ~ 1.18 μs. Compared with other experiments, this experiment further and more accurately studied the effects of dispersion, group delay and phase on actively Q-switched pulses. Because of the half-open cavity and erbium-doped fiber gain, the laser threshold is suppressed to 25 mW. The powers distribution on the wavelengths are uniform, and the amplitude difference between the ten wavelengths is < 2 dB. The side-mode suppression ratio of the laser after equalization is about 25 dB. When a triangle waveform is applied to the EOM, a dark pulse sequence output can be obtained. The proposed multi-wavelength actively Q-switched random fiber laser has the advantages of simple structure, low threshold and high stability.

我们提出了一种基于实时可配置波形器和电光调制器的多波长主动 Q 开关随机光纤激光器,并进行了实验演示。激光器的随机反馈由单模光纤产生的瑞利散射提供。波形器不仅充当多通道滤波器,还能在激光腔中引入与波长有关的损耗,从而抑制掺铒光纤均匀展宽引起的模式竞争和瑞利散射引起的功率不平衡。通过 Waveshaper 可以引入附加色散、群延迟、相位等参数,然后研究色散等附加量对主动 Q 开关随机光纤激光器的影响。在实验中,当附加色散在-200 ~ 200 ps/nm范围内变化时,主动Q开关的脉冲宽度可在1.01 ~ 1.18 μs之间变化。与其他实验相比,本实验进一步更准确地研究了色散、群延迟和相位对主动 Q 开关脉冲的影响。由于采用了半开腔和掺铒光纤增益,激光阈值被抑制到 25 mW。各波长上的功率分布均匀,十个波长之间的振幅差为 2 dB。均衡后的激光侧模抑制比约为 25 dB。当在 EOM 上施加三角波形时,可获得暗脉冲序列输出。所提出的多波长主动调 Q 随机光纤激光器具有结构简单、阈值低、稳定性高等优点。
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引用次数: 0
Electrical and thermoelectrical conductivity of sprayed MgxCo3-xO4 thin films 喷涂 MgxCo3-xO4 薄膜的电导率和热导率
IF 3.3 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-23 DOI: 10.1007/s11082-024-07761-1
L. Soussi, C. Louardi, T. Garmim, N. Benaissa, M. Bouzidi, O. Zahot, A. El,  Bachiri, A. Louardi, Z. ElJouad, H. Erguig

The effect of Mg substitution on the structural, morphological and electrical properties of sprayed magnesium cobalt oxide (MgxCo3-xO4) thin films (0 ≤ x ≤ 1) have been studed using X-ray diffraction (XRD), scanning electron microscopy, compositional analysis with EDS technique and four probe method for the electric conductivity measurements. XRD evaluation exhibits that MgxCo3-xO4 thin films are polycrystalline with spinel cubic structure. The EDS study confirms the presence of Mg and Co in the substituted films with the same concentrations as in the starting solution confirming the formation of MgxCo3-xO4 thin films. The effect of temperature on the dc conductivity reveals that the electrical transport mechanism in MgxCo3-xO4 thin films is based on the three-dimensional Mott’s variable-range hopping model. The density of states, the hopping distance, and the hopping energy have been successfully evaluated.

利用 X 射线衍射 (XRD)、扫描电子显微镜、EDS 技术的成分分析和四探针电导率测量法,研究了镁替代物对喷涂氧化镁钴(MgxCo3-xO4)薄膜(0 ≤ x ≤ 1)的结构、形态和电学特性的影响。X 射线衍射评估表明,MgxCo3-xO4 薄膜是多晶体,具有尖晶立方结构。EDS 研究证实,替代薄膜中存在与起始溶液浓度相同的镁和钴,从而确认了 MgxCo3-xO4 薄膜的形成。温度对直流电导的影响表明,MgxCo3-xO4 薄膜中的电传输机制是基于三维莫特变程跳变模型。研究成功地评估了态密度、跳变距离和跳变能量。
{"title":"Electrical and thermoelectrical conductivity of sprayed MgxCo3-xO4 thin films","authors":"L. Soussi,&nbsp;C. Louardi,&nbsp;T. Garmim,&nbsp;N. Benaissa,&nbsp;M. Bouzidi,&nbsp;O. Zahot,&nbsp;A. El,&nbsp; Bachiri,&nbsp;A. Louardi,&nbsp;Z. ElJouad,&nbsp;H. Erguig","doi":"10.1007/s11082-024-07761-1","DOIUrl":"10.1007/s11082-024-07761-1","url":null,"abstract":"<div><p>The effect of Mg substitution on the structural, morphological and electrical properties of sprayed magnesium cobalt oxide (Mg<sub>x</sub>Co<sub>3-x</sub>O<sub>4</sub>) thin films (0 ≤ x ≤ 1) have been studed using X-ray diffraction (XRD), scanning electron microscopy, compositional analysis with EDS technique and four probe method for the electric conductivity measurements. XRD evaluation exhibits that Mg<sub>x</sub>Co<sub>3-x</sub>O<sub>4</sub> thin films are polycrystalline with spinel cubic structure. The EDS study confirms the presence of Mg and Co in the substituted films with the same concentrations as in the starting solution confirming the formation of Mg<sub>x</sub>Co<sub>3-x</sub>O<sub>4</sub> thin films. The effect of temperature on the dc conductivity reveals that the electrical transport mechanism in Mg<sub>x</sub>Co<sub>3-x</sub>O<sub>4</sub> thin films is based on the three-dimensional Mott’s variable-range hopping model. The density of states, the hopping distance, and the hopping energy have been successfully evaluated.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"56 12","pages":""},"PeriodicalIF":3.3,"publicationDate":"2024-11-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142691997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of nanostructured Cu3SnS4 thin films through annealing of the stack of precursors for photonic applications 通过对用于光子应用的前驱体堆栈进行退火处理,开发出纳米结构的 Cu3SnS4 薄膜
IF 3.3 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-23 DOI: 10.1007/s11082-024-07709-5
Zakir Hussain, Naresh Padha, Arun Banotra

The stack of copper (Cu), tin (Sn), and sulfur (S) precursor layers was deposited on a Corning 2947 substrate using the thermal evaporation method under a vacuum of approximately 2 × 10–4 Pa, employing the sequentially evaporated layer deposition (SELD) technique. The as-deposited stack was annealed at 623–723 K under a vacuum of approximately 2 × 10⁻1 Pa to achieve the Cu3SnS4 phase. The stack exhibits amorphous behaviour, while films grown between 623 and 723 K attain nanostructured Cu3SnS4 (CTS) form. The influence of TA on the characteristics of the Cu3SnS4 layers was investigated through structural, morphological, compositional, optical, and electrical analyses. The annealed CTS films crystallize in a tetragonal crystal system with the space group I42 m (121). The grown films exhibit granular structures, with particles synthesized at 673 K demonstrating increased size. The bandgap (Eg) of the films decreases from 2.13 eV to 1.78 eV, while the absorption coefficient (α) ranges from 1 × 105 to 3 × 105 cm−1, as the annealing temperature (TA) increases from 623 to 723 K. At 673 K, the low resistivity of 9.37 × 10⁻3 Ω-cm, high mobility of 56.4 cm2/V-s, and acceptor concentration of 1.19 × 1019 cm⁻3 result from the increased crystallite size, which reduces grain boundary scattering. Thus, Cu3SnS4 is a promising absorber layer for thin-film solar cells due to its tunable bandgap, high optical absorption, low cost, and the use of earth-abundant elements. This study successfully advances photovoltaic technology by developing an economically viable alternative material for solar cell absorber layers, paving the way for large-scale solar cell production.

在约 2 × 10-4 Pa 的真空条件下,采用热蒸发法在康宁 2947 衬底上沉积了铜 (Cu)、锡 (Sn) 和硫 (S) 前驱体层,并采用了顺序蒸发层沉积 (SELD) 技术。在约 2 × 10-1 Pa 的真空条件下,在 623-723 K 的温度下对沉积的叠层进行退火处理,以获得 Cu3SnS4 相。叠层呈现非晶态,而在 623 至 723 K 之间生长的薄膜则呈现纳米结构的 Cu3SnS4(CTS)形态。通过结构、形态、成分、光学和电学分析,研究了 TA 对 Cu3SnS4 层特性的影响。退火后的 CTS 薄膜在空间群为 I42 m (121) 的四方晶系中结晶。生长出来的薄膜呈现颗粒状结构,在 673 K 下合成的颗粒尺寸增大。当退火温度(TA)从 623 K 升至 723 K 时,薄膜的带隙(Eg)从 2.13 eV 降至 1.78 eV,而吸收系数(α)则从 1 × 105 cm-1 升至 3 × 105 cm-1。在 673 K 时,由于晶体尺寸增大,晶界散射减少,因此电阻率较低,为 9.37 × 10-3 Ω-cm,迁移率较高,为 56.4 cm2/V-s,受体浓度为 1.19 × 1019 cm-3。因此,Cu3SnS4 因其可调带隙、高光吸收、低成本和使用地球富集元素而成为薄膜太阳能电池的一种前景广阔的吸收层。这项研究通过开发一种经济上可行的太阳能电池吸收层替代材料,成功地推动了光伏技术的发展,为太阳能电池的大规模生产铺平了道路。
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引用次数: 0
Correction: Investigation on optical properties of lead-free Cs3Bi2Br9 perovskite derivative quantum dots synthesised via modified LARP method 更正:通过改良 LARP 方法合成的无铅 Cs3Bi2Br9 包晶衍生物量子点的光学特性研究
IF 3.3 3区 工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC Pub Date : 2024-11-23 DOI: 10.1007/s11082-024-07819-0
Aswathi K. V., Shanthi Subashchandran, Pandiyarajan Mariyappan
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Optical and Quantum Electronics
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