Continuous photocatalytic C–C coupling achieved using palladium anchored to a covalent organic framework†

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2025-04-14 DOI:10.1039/d4cc06528j
Chao Ma , Zhe Wu , Yi-Tong Hou , Shao-Xuan Xiong , Li-Hua Ma , Zhi-Ming Zhang , Tong-Bu Lu , Song Guo
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Abstract

We firstly reported a single-atom palladium photocatalyst, Pd-Ace-COF, for a continuous C–C coupling reaction. Under visible light irradiation, Pd-Ace-COF efficiently drives C–C coupling to form biphenyl with a >99% yield. Impressively, Pd-Ace-COF exhibits good stability and high activity in the continuous-flow reactor, highlighting its great potential for practical applications.

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钯单原子锚定共价有机骨架连续光催化C-C偶联反应
我们首次报道了一种用于连续C-C偶联反应的单原子钯光催化剂Pd-Ace-COF。在可见光照射下,Pd-Ace-COF高效驱动C-C偶联生成联苯,产率达99%。令人印象深刻的是,Pd-Ace-COF在连续流反应器中表现出良好的稳定性和高活性,显示出其巨大的实际应用潜力。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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