Chao Ma , Zhe Wu , Yi-Tong Hou , Shao-Xuan Xiong , Li-Hua Ma , Zhi-Ming Zhang , Tong-Bu Lu , Song Guo
{"title":"Continuous photocatalytic C–C coupling achieved using palladium anchored to a covalent organic framework†","authors":"Chao Ma , Zhe Wu , Yi-Tong Hou , Shao-Xuan Xiong , Li-Hua Ma , Zhi-Ming Zhang , Tong-Bu Lu , Song Guo","doi":"10.1039/d4cc06528j","DOIUrl":null,"url":null,"abstract":"<div><div>We firstly reported a single-atom palladium photocatalyst, Pd-Ace-COF, for a continuous C–C coupling reaction. Under visible light irradiation, Pd-Ace-COF efficiently drives C–C coupling to form biphenyl with a >99% yield. Impressively, Pd-Ace-COF exhibits good stability and high activity in the continuous-flow reactor, highlighting its great potential for practical applications.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 39","pages":"Pages 7085-7088"},"PeriodicalIF":4.2000,"publicationDate":"2025-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734525007633","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
We firstly reported a single-atom palladium photocatalyst, Pd-Ace-COF, for a continuous C–C coupling reaction. Under visible light irradiation, Pd-Ace-COF efficiently drives C–C coupling to form biphenyl with a >99% yield. Impressively, Pd-Ace-COF exhibits good stability and high activity in the continuous-flow reactor, highlighting its great potential for practical applications.
期刊介绍:
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