Flexible and freestanding solar cells based on metal organic chemical vapour deposition- grown graphene

IF 2.5 4区 化学 Q2 Engineering Chemical Papers Pub Date : 2025-01-28 DOI:10.1007/s11696-025-03910-2
Athil S. Al-Ezzi, M. N. M. Ansari, Nadia Tan
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Abstract

The prospective uses of flexible and freestanding solar cells in lightweight, portable, and flexible energy-harvesting systems have attracted a lot of attention over the last few years. Metal organic chemical vapour deposition (MOCVD) stands out as a crucial approach for producing high-quality gallium arsenide (GaAs) films among the different processes used to produce high-performance thin-film solar cells. This review highlights the main growth processes, issues and crucial factors that affect material quality and device efficiency, while it critically investigates the use of MOCVD to produce flexible and freestanding GaAs-based solar cells. The optimization of MOCVD growth conditions, such as substrate selection, precursor flow rates, and temperature control, is given particular attention. The paper also looks at recent developments in remote epitaxy, a promising method that removes the limitations of conventional substrate-lattice matching and facilitates the production of freestanding GaAs films. The review also outlines the main obstacles, such as strain, scalability problems, and material imperfections, and it addresses performance metrics like efficiency and stability. Finally, future research and development efforts are described, with a focus on the necessity of additional growth technique optimization, the investigation of novel substrate materials, and improvements in the marketing of flexible GaAs solar cells.

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基于金属有机化学气相沉积-生长石墨烯的柔性和独立式太阳能电池
在过去的几年里,柔性和独立式太阳能电池在轻质、便携和灵活的能量收集系统中的应用吸引了很多关注。金属有机化学气相沉积(MOCVD)作为生产高质量砷化镓(GaAs)薄膜的关键方法,在用于生产高性能薄膜太阳能电池的不同工艺中脱颖而出。这篇综述强调了影响材料质量和器件效率的主要生长过程、问题和关键因素,同时批判性地研究了使用MOCVD生产柔性和独立式gaas基太阳能电池。MOCVD生长条件的优化,如衬底选择、前驱体流速和温度控制,被给予了特别的关注。本文还研究了远程外延的最新发展,这是一种很有前途的方法,它消除了传统衬底-晶格匹配的局限性,并促进了独立GaAs薄膜的生产。该综述还概述了主要障碍,如应变、可扩展性问题和材料缺陷,并解决了效率和稳定性等性能指标。最后,描述了未来的研究和发展努力,重点是额外的生长技术优化的必要性,新型衬底材料的研究,以及柔性砷化镓太阳能电池的营销改进。
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来源期刊
Chemical Papers
Chemical Papers Chemical Engineering-General Chemical Engineering
CiteScore
3.30
自引率
4.50%
发文量
590
期刊介绍: Chemical Papers is a peer-reviewed, international journal devoted to basic and applied chemical research. It has a broad scope covering the chemical sciences, but favors interdisciplinary research and studies that bring chemistry together with other disciplines.
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