Microstructural evolution and mechanism of a gradient multilayer CrN coating during isothermal oxidation

IF 6.1 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS Surface & Coatings Technology Pub Date : 2025-03-30 DOI:10.1016/j.surfcoat.2025.132109
Shupeng Xu , Yu Xia , Jian Peng , Qiang Shen , Chuanbin Wang
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Abstract

The isothermal oxidation behavior, kinetics, and microstructural evolution of a gradient multilayer CrN coating deposited on 304 stainless steel were systematically investigated. The CrN coating demonstrated superior oxidation resistance compared to conventional Cr and CrN coatings, as evidenced by a lower weight gain over prolonged oxidation. The gradient structure of the coating evolved into a homogeneous multilayer, which effectively delayed the oxidation by hindering the diffusion of oxygen. Additionally, the introduction of a Cr bonding layer not only facilitated the formation of a robust interdiffusion zone with the substrate but also enhanced the coating's adhesion, contributing to its long-term stability.
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等温氧化过程中梯度多层CrN涂层的组织演变及机理
系统地研究了304不锈钢表面多层梯度CrN涂层的等温氧化行为、动力学和显微组织演变。与传统的Cr和CrN涂层相比,CrN涂层表现出更好的抗氧化性,因为在长时间氧化过程中重量增加较少。涂层的梯度结构演变成均匀的多层,通过阻碍氧的扩散有效地延缓了氧化。此外,Cr键合层的引入不仅有助于与基体形成坚固的互扩散区,而且还增强了涂层的附着力,有助于其长期稳定性。
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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