Synthesis and performance research of an AIE molecule

IF 4.7 3区 化学 Q2 CHEMISTRY, PHYSICAL Journal of Photochemistry and Photobiology A-chemistry Pub Date : 2025-10-01 Epub Date: 2025-04-02 DOI:10.1016/j.jphotochem.2025.116420
Yuehua Liang, Jiuzhi Wei, Juan Zhang, Tingting Zhang, Yanyan Li, Caiyuan Guo, Enke Feng, Xinxian Ma, Xinning Han
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Abstract

This study utilized a simple design principle of using methoxy groups to restrict molecular rotation, converting ACQ molecules (BS-1) into AIE (BS-2) light sources. The BS-2 can recognize Al3+ and assemble into a supramolecular metallogel (BS-2-Al@gel). Furthermore, using the BS-2-Al3+ complex as a donor and Rhodamine 6G as acceptor, a artificial light–harvesting systems (ALHSs) has been prepared.

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一种AIE分子的合成与性能研究
本研究利用甲氧基限制分子旋转的简单设计原理,将ACQ分子(BS-1)转化为AIE (BS-2)光源。BS-2可以识别Al3+并组装成超分子金属凝胶(BS-2-Al@gel)。此外,以BS-2-Al3+配合物为供体,罗丹明6G为受体,制备了人工光收集系统(alhs)。
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来源期刊
CiteScore
7.90
自引率
7.00%
发文量
580
审稿时长
48 days
期刊介绍: JPPA publishes the results of fundamental studies on all aspects of chemical phenomena induced by interactions between light and molecules/matter of all kinds. All systems capable of being described at the molecular or integrated multimolecular level are appropriate for the journal. This includes all molecular chemical species as well as biomolecular, supramolecular, polymer and other macromolecular systems, as well as solid state photochemistry. In addition, the journal publishes studies of semiconductor and other photoactive organic and inorganic materials, photocatalysis (organic, inorganic, supramolecular and superconductor). The scope includes condensed and gas phase photochemistry, as well as synchrotron radiation chemistry. A broad range of processes and techniques in photochemistry are covered such as light induced energy, electron and proton transfer; nonlinear photochemical behavior; mechanistic investigation of photochemical reactions and identification of the products of photochemical reactions; quantum yield determinations and measurements of rate constants for primary and secondary photochemical processes; steady-state and time-resolved emission, ultrafast spectroscopic methods, single molecule spectroscopy, time resolved X-ray diffraction, luminescence microscopy, and scattering spectroscopy applied to photochemistry. Papers in emerging and applied areas such as luminescent sensors, electroluminescence, solar energy conversion, atmospheric photochemistry, environmental remediation, and related photocatalytic chemistry are also welcome.
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