Highly Sensitive Triethylamine Sensors Enabled by Co3O4/ZnO p-n Heterojunctions

IF 6.9 2区 材料科学 Q2 CHEMISTRY, PHYSICAL Applied Surface Science Pub Date : 2025-04-05 DOI:10.1016/j.apsusc.2025.163092
Lin Wang , Haili Huang , Dongdong Zhang , Hung-Chun Wu , Meiling Li , Huilin Hou , Weiyou Yang , Xuhui Yu , Zonghua Wang
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Abstract

Triethylamine (TEA) is a typically volatile organic compound that poses significant environmental and health risks, due to its high toxicity and volatility. Currently, the exploration of TEA sensors based on semiconductor ZnO is still suffered by their intrinsically low sensitivity, slow response/recovery times, and poor selectivity. Herein, we develop the highly-sensitive TEA sensors based on rationally-designed Co3O4/ZnO p-n heterojunctions, in which the clustered Co3O4 are incorporated into porous ZnO nanosheets. As a result, at the given operating temperature of 260 °C, the as-constructed sensors exhibit an overall enhanced performance with an excellent response of 140.5 to 100 ppm TEA, swift response/recovery times of 6/60 s and high selectivity, representing their promise toward practical applications in advanced TEA sensors.

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由Co3O4/ZnO p-n异质结实现的高灵敏度三乙胺传感器
三乙胺(TEA)是一种典型的挥发性有机化合物,由于其高毒性和挥发性,对环境和健康构成重大风险。目前,基于半导体ZnO的TEA传感器的开发仍然存在固有的灵敏度低、响应/恢复时间慢、选择性差的问题。在此,我们基于合理设计的Co3O4/ZnO p-n异质结开发了高灵敏度的TEA传感器,其中聚集的Co3O4被纳入多孔ZnO纳米片中。因此,在260 °C的给定工作温度下,构建的传感器表现出整体增强的性能,具有140.5至100 ppm TEA的出色响应,6/60 s的快速响应/恢复时间和高选择性,代表了它们在先进TEA传感器中的实际应用前景。
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来源期刊
Applied Surface Science
Applied Surface Science 工程技术-材料科学:膜
CiteScore
12.50
自引率
7.50%
发文量
3393
审稿时长
67 days
期刊介绍: Applied Surface Science covers topics contributing to a better understanding of surfaces, interfaces, nanostructures and their applications. The journal is concerned with scientific research on the atomic and molecular level of material properties determined with specific surface analytical techniques and/or computational methods, as well as the processing of such structures.
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