Enhanced microstructure, mechanical, and tribological properties of Al, Ti, and nano-hBN-modified CoCrFeMnNi high-entropy alloy composites at elevated temperatures

IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Wear Pub Date : 2025-04-03 DOI:10.1016/j.wear.2025.206055
Wenbo Ma , Yubo Zhao , Magdalena Łępicka , Oleksandr Tisov
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Abstract

This study investigates the microstructure, mechanical properties, and tribological performance against Si3N4 ball of CoCrFeMnNi high-entropy alloy (HEA) matrix composites modified with 2 wt% Al, 2 wt% Ti, and varying nano-hBN contents. Spark plasma sintering (SPS) was employed to achieve grain refinement, the formation of Cr2B and TiN phases, and improved hardness and yield strength. The composites demonstrated exceptional wear resistance, especially at elevated temperatures. At 900 °C, a continuous oxide layer enhanced wear protection, while at room temperature (RT), the hBN lubrication film reduced wear. The 0.5 wt% hBN composite exhibited optimal performance, combining reduced wear rates, improved mechanical properties, and a consistent tribological response across a wide temperature range.
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高温下Al、Ti和纳米hbn改性CoCrFeMnNi高熵合金复合材料的显微组织、力学和摩擦学性能增强
本研究研究了CoCrFeMnNi高熵合金(HEA)基复合材料的显微组织、力学性能和抗Si3N4球的摩擦学性能,这些复合材料分别由2wt % Al、2wt % Ti和不同纳米hbn含量改性而成。采用放电等离子烧结(SPS)使合金晶粒细化,形成Cr2B相和TiN相,提高了硬度和屈服强度。复合材料表现出优异的耐磨性,特别是在高温下。在900°C时,连续氧化层增强了磨损保护,而在室温(RT)下,hBN润滑膜减少了磨损。0.5 wt%的hBN复合材料表现出最佳的性能,同时降低了磨损率,提高了机械性能,并且在很宽的温度范围内具有一致的摩擦学响应。
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来源期刊
Wear
Wear 工程技术-材料科学:综合
CiteScore
8.80
自引率
8.00%
发文量
280
审稿时长
47 days
期刊介绍: Wear journal is dedicated to the advancement of basic and applied knowledge concerning the nature of wear of materials. Broadly, topics of interest range from development of fundamental understanding of the mechanisms of wear to innovative solutions to practical engineering problems. Authors of experimental studies are expected to comment on the repeatability of the data, and whenever possible, conduct multiple measurements under similar testing conditions. Further, Wear embraces the highest standards of professional ethics, and the detection of matching content, either in written or graphical form, from other publications by the current authors or by others, may result in rejection.
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