Ultra-low friction, ultra-fast response and low-VOC self-lubricating coating based on oil-filled silica microcapsules

IF 6.1 1区 工程技术 Q1 ENGINEERING, MECHANICAL Tribology International Pub Date : 2025-04-05 DOI:10.1016/j.triboint.2025.110701
Yanliang Shen , Yanhua Wang , Chen Zhao , Xingwei Wang , Qiangliang Yu , Meirong Cai , Bo Yu , Feng Zhou
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Abstract

A complete silica microcapsule filled with PAO6 oil was synthesized by emulsion-templated sol-gel method. The average diameter of microcapsule was about 20 µm, with encapsulation capacity of 70 %. The microcapsules were well-dispersed in aqueous solution and fully compatible with waterborne epoxy emulsion, making it suitable for building VOC-free self-lubricating coatings. With 5 wt% microcapsule, the self-lubricating coating achieved an exceptionally low friction coefficient at about 0.02, approximately 2.6 % of that of the blank coating without microcapsules. The wear volume could barely be measured. The ultra-fast response ability was robust, as confirmed by the negligible running time throughout the continuous start-stop sliding tests. This oil-filled silica microcapsule has great potential for developing high performance and VOC-free self-lubricating coatings.
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基于充油二氧化硅微胶囊的超低摩擦、超快速响应、低voc自润滑涂层
采用乳液模板溶胶-凝胶法制备了以PAO6油填充的完整二氧化硅微胶囊。微胶囊的平均直径约为20 µm,包封率为70 %。微胶囊在水溶液中分散良好,与水性环氧乳液完全相容,适用于构建无voc自润滑涂料。含有5 wt%微胶囊的自润滑涂层获得了极低的摩擦系数,约为0.02,约为没有微胶囊的空白涂层的2.6 %。磨损量几乎无法测量。在连续的启停滑动测试中,运行时间可以忽略不计,证实了超快速响应能力的鲁棒性。这种充油二氧化硅微胶囊具有开发高性能、无voc自润滑涂层的巨大潜力。
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来源期刊
Tribology International
Tribology International 工程技术-工程:机械
CiteScore
10.10
自引率
16.10%
发文量
627
审稿时长
35 days
期刊介绍: Tribology is the science of rubbing surfaces and contributes to every facet of our everyday life, from live cell friction to engine lubrication and seismology. As such tribology is truly multidisciplinary and this extraordinary breadth of scientific interest is reflected in the scope of Tribology International. Tribology International seeks to publish original research papers of the highest scientific quality to provide an archival resource for scientists from all backgrounds. Written contributions are invited reporting experimental and modelling studies both in established areas of tribology and emerging fields. Scientific topics include the physics or chemistry of tribo-surfaces, bio-tribology, surface engineering and materials, contact mechanics, nano-tribology, lubricants and hydrodynamic lubrication.
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