Chong Ma, Yihao Xia, Xue Ding, Lei Qin and Zhiping Zheng
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引用次数: 0
Abstract
Ruthenium(II) complexes with tridentate pincer ligands were tested for catalytic hydrogen production from aqueous-phase reforming of methanol. The most sterically hindered complex (C4) achieved a turnover number of 14 050. Mechanistic studies revealed that ligand dissociation and substitution play crucial roles in activating the catalyst and transforming substrates.
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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