{"title":"The facile preparation of mixed-valence metal–organic frameworks through reduction†","authors":"Yunshi Wang, Cen Chen and Liying Zhang","doi":"10.1039/D5CC00031A","DOIUrl":null,"url":null,"abstract":"<p >A facile strategy was applied to prepare Cu(<small>I</small>)/Cu(<small>II</small>) MOFs, where the Cu(<small>I</small>) amount and porous structure can be adjusted by the degree of reduction and the size of HKUST-1, by partially reducing HKUST-1 with hydrazine hydrate at room temperature. The Cu(<small>I</small>)/Cu(<small>II</small>) MOFs exhibit excellent catalytic capability in the Cu(<small>I</small>)-catalyzed azide alkyne cycloaddition.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" 38","pages":" 6929-6932"},"PeriodicalIF":4.2000,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/cc/d5cc00031a","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A facile strategy was applied to prepare Cu(I)/Cu(II) MOFs, where the Cu(I) amount and porous structure can be adjusted by the degree of reduction and the size of HKUST-1, by partially reducing HKUST-1 with hydrazine hydrate at room temperature. The Cu(I)/Cu(II) MOFs exhibit excellent catalytic capability in the Cu(I)-catalyzed azide alkyne cycloaddition.
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