Enhancing interfacial strength of DLC films on plasma-nitrided stainless steel

IF 6.1 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS Surface & Coatings Technology Pub Date : 2025-04-02 DOI:10.1016/j.surfcoat.2025.132106
Abdelrahman Farghali , Tatsuhiko Aizawa , Junho Choi
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Abstract

An interfacial toughness of diamond-like carbon (DLC) films onto the stainless steel substrates is of progressive importance due to the countless tribological advantages of DLC in recent industries. The purpose of this article is to enhance the adhesion strength of DLC amorphous film on martensite stainless steel by introducing two different layers. A combination of nitrogen supersaturation layer and SiCx:H interlayer film were utilized to achieve this purpose. The nanograined, hard nitrogen-supersaturated layer, acted as a transition zone, having more homogenous load-bearing capacity than all coatings onto the non-nitrided substrate. Moreover, SiCx:H interlayer attains SiN and CN bonds between the nitrogen-supersaturated layer and SiCx:H interlayer. These bonds have a direct influence in increasing the number of stable sp3 hybridization bonds between these two layers which ultimately further improve the interfacial strength.
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提高等离子体氮化不锈钢表面DLC膜的界面强度
类金刚石(DLC)薄膜在不锈钢衬底上的界面韧性越来越重要,因为DLC在最近的工业中具有无数的摩擦学优势。本文的目的是通过引入两种不同的层来提高DLC非晶膜在马氏体不锈钢上的附着强度。利用氮过饱和层和SiCx:H层间膜的组合来实现这一目的。纳米颗粒、坚硬的氮过饱和层作为过渡区,比非氮化基底上的所有涂层具有更均匀的承载能力。此外,SiCx:H间层在氮过饱和层和SiCx:H间层之间形成了SiN和CN键。这些键对增加两层间稳定的sp3杂化键的数量有直接影响,最终进一步提高界面强度。
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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