Exploring Forest Soils Variability Based on Physicochemical Properties Using Correspondence Analysis and Classification and Regression Tree for Forensic Provenance Analysis

IF 1.1 4区 化学 Q4 CHEMISTRY, ANALYTICAL Journal of Analytical Chemistry Pub Date : 2025-04-15 DOI:10.1134/S1061934824701661
Nadirah Abd Hamid, Muhamad Hilmi Baba, Hukil Sino, Azhar Abdul Halim, Loong Chuen Lee
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Abstract

Soils on forest lands are likely characterized by high organic matter content and a diversity of nutrients. Thus, differentiating forest soils from different sites of origin is a challenging task. This study aims to assess the variability of 163 forest soils based on two easily measured physiochemical properties: soil color and pH. The soil samples were collected from 11 different sites across six states in Malaysia. Soil color was recorded under both air-dry and moistened conditions based on the Munsell Soil Color Chart. Meanwhile, soil pH was determined using a soil-to-water ratio of 1 : 20 (w/v). The association between the source origins and the physiochemical properties of the soils was assessed using simple correspondence analysis. Classification of the soils by the type of anthropogenic activities, according to pH, was further modeled using the classification and regression tree algorithm. The results showed that soils from ecotourism sites tended to be less acidic than those from reserved forest sites. Meanwhile, soils from forest lands used for hiking showed acidity levels between the two types of sites. On the other hand, variability in soil color by the source origin was found to be insignificant. In conclusion, forest soils could be further classified according to the type of anthropogenic activities, which are partly governed by the type and magnitude of human activities.

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基于对应分析和分类回归树法证物源分析的森林土壤理化性质变异研究
森林土地上的土壤可能具有有机物含量高和养分多样性的特点。因此,区分不同产地的森林土壤是一项具有挑战性的任务。这项研究的目的是基于两种容易测量的理化性质:土壤颜色和ph值来评估163种森林土壤的可变性。土壤样本是从马来西亚6个州的11个不同地点收集的。根据孟塞尔土壤颜色图记录了风干和潮湿条件下的土壤颜色。同时,采用1:20 (w/v)的土水比测定土壤pH值。用简单的对应分析方法评价了土壤的源源和理化性质之间的关系。利用分类和回归树算法进一步模拟了土壤的人为活动类型,并根据pH值进行了分类。结果表明,生态旅游地土壤酸性倾向于低于森林保护区土壤。与此同时,用于徒步旅行的林地土壤显示出两种地点之间的酸度水平。另一方面,土壤颜色的变化被发现不显著。综上所述,森林土壤可以根据人类活动的类型进一步分类,人类活动的类型和程度在一定程度上决定了森林土壤的分类。
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来源期刊
Journal of Analytical Chemistry
Journal of Analytical Chemistry 化学-分析化学
CiteScore
2.10
自引率
9.10%
发文量
146
审稿时长
13 months
期刊介绍: The Journal of Analytical Chemistry is an international peer reviewed journal that covers theoretical and applied aspects of analytical chemistry; it informs the reader about new achievements in analytical methods, instruments and reagents. Ample space is devoted to problems arising in the analysis of vital media such as water and air. Consideration is given to the detection and determination of metal ions, anions, and various organic substances. The journal welcomes manuscripts from all countries in the English or Russian language.
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