{"title":"Hydrated Calcium Silicate (C–S–H) Improves the Performance of Stone Powder as Cement Admixtures","authors":"Ruiling Jin, Qin Xu, Xiaodong Yang","doi":"10.1021/acs.langmuir.5c00695","DOIUrl":null,"url":null,"abstract":"The low pozzolanic activity of recycled stone powder limits its application in cement-based materials. Calcium silicate hydrate (CSH) is one of the hydration products of cement and also has the function of promoting hydration and improving strength. Therefore, the behavior of CSH in enhancing the activity of stone powder has been studied, including the workability and mechanical properties, and the mechanism of activity enhancement has been explained at the microscopic level. The results showed that when the amount of stone powder was 30%, the setting time was shortened by 26.14% to 34.34%, the slump increased by 7.89%, and the compressive strength at 3 and 28 days decreased by 40.94% and 37.99%, respectively. On this basis, when CSH was added at a dosage of 1%, compared with the specimen with a dosage of 30% stone powder, the setting time was shortened by 18.29% ∼ 21.53%, the slump was increased by 2.44%, and the compressive strength at 3 and 28 d was increased by 15.95% and 16.25%, respectively. The pozzolanic activity of stone powder has increased from 62.00% to 71.82%, reaching the pozzolanic activity level of fly ash. The mechanism of CSH enhancing pozzolanic activity was explained at the micro level, which broadened the application channels for the high-dosage application of stone powder.","PeriodicalId":50,"journal":{"name":"Langmuir","volume":"50 1","pages":""},"PeriodicalIF":3.9000,"publicationDate":"2025-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Langmuir","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.langmuir.5c00695","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The low pozzolanic activity of recycled stone powder limits its application in cement-based materials. Calcium silicate hydrate (CSH) is one of the hydration products of cement and also has the function of promoting hydration and improving strength. Therefore, the behavior of CSH in enhancing the activity of stone powder has been studied, including the workability and mechanical properties, and the mechanism of activity enhancement has been explained at the microscopic level. The results showed that when the amount of stone powder was 30%, the setting time was shortened by 26.14% to 34.34%, the slump increased by 7.89%, and the compressive strength at 3 and 28 days decreased by 40.94% and 37.99%, respectively. On this basis, when CSH was added at a dosage of 1%, compared with the specimen with a dosage of 30% stone powder, the setting time was shortened by 18.29% ∼ 21.53%, the slump was increased by 2.44%, and the compressive strength at 3 and 28 d was increased by 15.95% and 16.25%, respectively. The pozzolanic activity of stone powder has increased from 62.00% to 71.82%, reaching the pozzolanic activity level of fly ash. The mechanism of CSH enhancing pozzolanic activity was explained at the micro level, which broadened the application channels for the high-dosage application of stone powder.
期刊介绍:
Langmuir is an interdisciplinary journal publishing articles in the following subject categories:
Colloids: surfactants and self-assembly, dispersions, emulsions, foams
Interfaces: adsorption, reactions, films, forces
Biological Interfaces: biocolloids, biomolecular and biomimetic materials
Materials: nano- and mesostructured materials, polymers, gels, liquid crystals
Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry
Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals
However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do?
Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*.
This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).