Covalent triazine frameworks: Fabrication for energy conversion

IF 23.5 1区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Coordination Chemistry Reviews Pub Date : 2025-04-17 DOI:10.1016/j.ccr.2025.216703
Zikang Lei , Manying Liu , Yange Zhang , Linke Li , Shuang-Quan Zang , Zhi Zheng
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Abstract

Covalent triazine frameworks (CTFs) have been widely investigated for their potential applications in organic optoelectronics. While previous reviews have extensively covered the synthesis, characterization, and diverse applications of CTFs, there is still a notable lack of comprehensive analyses that delve into their crucial role in optoelectronic semiconductors. This review addresses this void by emphasizing the importance of CTFs in energy conversion processes. We provide an overview of how synthesis techniques can enhance CTF crystallinity, which is crucial for their performance in these processes due to their efficient ability to separate and transport charge carriers. Additionally, we explore the latest research progress in diverse areas such as photocatalytic carbon dioxide reduction, water splitting, hydrogen peroxide (H2O2) production, perovskite film quality enhancement, and solar cell power conversion efficiency (PCE) improvement.
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共价三嗪框架:用于能量转换的制备
共价三嗪框架(CTFs)因其在有机光电子学中的潜在应用而受到广泛的研究。虽然以前的综述广泛地涵盖了CTFs的合成,表征和各种应用,但仍然明显缺乏深入研究其在光电半导体中的关键作用的综合分析。本文通过强调CTFs在能量转换过程中的重要性来解决这一空白。我们概述了合成技术如何提高CTF结晶度,这对于CTF在这些工艺中的性能至关重要,因为它们具有有效分离和传输载流子的能力。此外,我们还探讨了光催化二氧化碳还原、水分解、过氧化氢(H2O2)生成、钙钛矿膜质量提高和太阳能电池功率转换效率(PCE)提高等各个领域的最新研究进展。
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来源期刊
Coordination Chemistry Reviews
Coordination Chemistry Reviews 化学-无机化学与核化学
CiteScore
34.30
自引率
5.30%
发文量
457
审稿时长
54 days
期刊介绍: Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.
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