Design strategies, luminescence mechanisms, and solid-state lighting applications of lanthanide-doped phosphorescent materials

Divya Prasanth , D.V. Sunitha , P. Ranjith Kumar , G.P. Darshan
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Abstract

Nanomaterials have emerged as an active area of research. This is because of their broad spectrum of applications such as sensors, white light emitting diodes (LEDs), electronic displays, and other optoelectronic devices in the optics and electronic industries owing to their size- and shape-dependent properties. The synthesis technique plays a crucial role in tuning the size and shape of the materials. Herein, we briefly describe these nanomaterials' fundamental aspects, properties, and applications. Various nanomaterial synthesis methods are discussed. Their advantages and disadvantages are highlighted in conjunction with the criteria for selecting a synthesis method. The principle underlying the sonochemical method and its applicability in synthesizing diverse sub-15 nm size nanoparticles (NPs) are presented. The main objective of this article is to review recent studies on lanthanide-doped nanophosphors and the various parameters that play key roles in achieving optimum luminescence emission. Both down-conversion and up-conversion mechanisms are discussed. The importance of the combinations and concentrations of the synthesizer/activator, color tuning, and host material are emphasized.

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稀土掺杂磷光材料的设计策略、发光机制及固态照明应用
纳米材料已成为一个活跃的研究领域。这是因为纳米材料的尺寸和形状特性决定了其广泛的应用范围,如光学和电子工业中的传感器、白光发光二极管(LED)、电子显示器和其他光电设备。合成技术在调整材料的尺寸和形状方面起着至关重要的作用。在此,我们将简要介绍这些纳米材料的基本方面、特性和应用。我们讨论了各种纳米材料的合成方法。结合选择合成方法的标准,重点介绍了它们的优缺点。介绍了声化学方法的基本原理及其在合成 15 纳米以下尺寸的各种纳米颗粒 (NPs) 中的适用性。本文的主要目的是回顾掺杂镧系元素的纳米磷的最新研究,以及在实现最佳发光发射方面起关键作用的各种参数。文章讨论了下转换和上转换机制。强调了合成/激活剂、颜色调节和宿主材料的组合和浓度的重要性。
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