Multicomponent Synthesis of S‑Vinyl Dithiocarbamates Using Vinyl Sulfonium Salts with CS2 and Amines

IF 2 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY ChemistrySelect Pub Date : 2025-04-16 DOI:10.1002/slct.202501354
Chengcheng Zhang, Yapeng Zhang, Jingfeng Lan, Bo Zhao, Jiaze Qin, Peihua Liu, Rulong Yan
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Abstract

A method for synthesizing dithiocarbamates via the ring-opening of vinyl sulfonium salts, employing CS2 and amines has been presented. The transformation can be performed rapidly at room temperature in ambient air without any additives. Additionally, the protocol features an extensive substrate range and simple reactive operations and affords the dithiocarbamates in a remarkably short time and elevated yields.

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用乙烯基磺酸盐与CS2和胺合成S -乙烯基二硫代氨基甲酸酯的多组分研究
介绍了以CS2和胺为原料,乙烯基磺酸盐开环合成二硫代氨基甲酸酯的方法。在室温下,在没有任何添加剂的环境空气中,可以快速地进行转化。此外,该方案具有广泛的底物范围和简单的反应操作,并在非常短的时间内提供二硫代氨基甲酸酯和提高产量。
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来源期刊
ChemistrySelect
ChemistrySelect Chemistry-General Chemistry
CiteScore
3.30
自引率
4.80%
发文量
1809
审稿时长
1.6 months
期刊介绍: ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.
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