Vijay S. Parmar, Gemma K. Gransbury, Sophie C. Corner, Wei-Hao Chou, Stephen Hill, Richard E. P. Winpenny, Nicholas F. Chilton and David P. Mills
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引用次数: 0
Abstract
Two heteroleptic octahedral Dy(III) cis-aryloxide complexes, [Dy(OPh*)2(THF)3X] {HOPh* = 2,6-bis(diphenyl-methyl)-4-tert-butylphenol; X = Cl (1), Br (2)}, have been characterised by multi-frequency electron paramagnetic resonance (EPR) spectroscopy to determine gz = 18.9(1) for 1 and 18.3(6) for 2. These are rare examples of Dy(III) single-molecule magnets that have observable EPR spectra.
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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