Hydrogen production and hybrid use of alkali metals in power generation and electric energy storage technologies using an electrochemical generator and gas turbine installation
{"title":"Hydrogen production and hybrid use of alkali metals in power generation and electric energy storage technologies using an electrochemical generator and gas turbine installation","authors":"S.E. Shcheklein, A.M. Dubinin, K.S. Iuzbashieva","doi":"10.1016/j.ijhydene.2025.04.149","DOIUrl":null,"url":null,"abstract":"<div><div>Hydrogen is an efficient energy carrier for heat and power technologies and electrochemical sources of electric current. The proposed technology eliminates the need for storage and transportation of hydrogen, and provides its production in the amount necessary for direct use at power plants. This article considers the possibility of using alkali metals as the most effective method of hydrogen production by reaction with water. The reaction product (alkali) is repeatedly reduced to pure metal by electrolysis at the expense of energy (during the period of night power failure of TPPs and NPPs) or at the expense of RES energy during the period of its natural availability (HPPs, PV plant, WPPs).</div><div>Calculated studies have shown that the process of water reduction by alkali metals is exothermic with the release of heat of high thermodynamic potential, which allows along with the direct conversion of hydrogen into electrical energy using fuel cells to realize additional production of electrical energy on the basis of thermodynamic Rankine or Brayton cycles.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"128 ","pages":"Pages 732-739"},"PeriodicalIF":8.3000,"publicationDate":"2025-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Hydrogen Energy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0360319925017744","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/4/19 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Hydrogen is an efficient energy carrier for heat and power technologies and electrochemical sources of electric current. The proposed technology eliminates the need for storage and transportation of hydrogen, and provides its production in the amount necessary for direct use at power plants. This article considers the possibility of using alkali metals as the most effective method of hydrogen production by reaction with water. The reaction product (alkali) is repeatedly reduced to pure metal by electrolysis at the expense of energy (during the period of night power failure of TPPs and NPPs) or at the expense of RES energy during the period of its natural availability (HPPs, PV plant, WPPs).
Calculated studies have shown that the process of water reduction by alkali metals is exothermic with the release of heat of high thermodynamic potential, which allows along with the direct conversion of hydrogen into electrical energy using fuel cells to realize additional production of electrical energy on the basis of thermodynamic Rankine or Brayton cycles.
期刊介绍:
The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc.
The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.