Hydrogen production and hybrid use of alkali metals in power generation and electric energy storage technologies using an electrochemical generator and gas turbine installation

IF 8.3 2区 工程技术 Q1 CHEMISTRY, PHYSICAL International Journal of Hydrogen Energy Pub Date : 2025-05-15 Epub Date: 2025-04-19 DOI:10.1016/j.ijhydene.2025.04.149
S.E. Shcheklein, A.M. Dubinin, K.S. Iuzbashieva
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Abstract

Hydrogen is an efficient energy carrier for heat and power technologies and electrochemical sources of electric current. The proposed technology eliminates the need for storage and transportation of hydrogen, and provides its production in the amount necessary for direct use at power plants. This article considers the possibility of using alkali metals as the most effective method of hydrogen production by reaction with water. The reaction product (alkali) is repeatedly reduced to pure metal by electrolysis at the expense of energy (during the period of night power failure of TPPs and NPPs) or at the expense of RES energy during the period of its natural availability (HPPs, PV plant, WPPs).
Calculated studies have shown that the process of water reduction by alkali metals is exothermic with the release of heat of high thermodynamic potential, which allows along with the direct conversion of hydrogen into electrical energy using fuel cells to realize additional production of electrical energy on the basis of thermodynamic Rankine or Brayton cycles.

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利用电化学发电机和燃气轮机装置在发电和电能储存技术中生产氢气和混合使用碱金属
氢是热电技术的有效能量载体和电流的电化学源。拟议中的技术消除了储存和运输氢气的需要,并提供了直接用于发电厂所需的氢气产量。本文考虑了利用碱金属作为与水反应制氢的最有效方法的可能性。反应产物(碱)通过电解反复还原为纯金属,其代价是消耗能源(在TPPs和NPPs的夜间停电期间)或消耗自然可用的可再生能源(HPPs、PV电站、WPPs)。计算研究表明,碱金属还原水的过程是放热的,释放出高热势的热,这使得利用燃料电池将氢直接转化为电能,在热力学朗肯循环或布雷顿循环的基础上实现额外的电能生产。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
International Journal of Hydrogen Energy
International Journal of Hydrogen Energy 工程技术-环境科学
CiteScore
13.50
自引率
25.00%
发文量
3502
审稿时长
60 days
期刊介绍: The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc. The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.
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