Study on the Downward and Upward Flame Spread Characteristics of Thermoplastic Thermal Insulation Materials After Light Aging

IF 2.8 3区 化学 Q2 POLYMER SCIENCE Journal of Applied Polymer Science Pub Date : 2025-02-23 DOI:10.1002/app.56907
Wenlong Zhang, Zhanxiao Chen, Rongkun Pan, Qingsheng Zhang, Hui Yu, Yanming Ding
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Abstract

Thermoplastic thermal insulation materials (TTIMs) in high-rise buildings are often exposed to ultraviolet radiation, different temperatures, and humidity environments, leading to light aging. Their performances, such as surface color and morphology, have changed, whereas their fire risk has not been reported. Especially, the fire hazard of TTIMs is always an essential issue for high-rise building fires. Therefore, it is necessary to study the fire risk of aging TTIMs. An accelerated aging experiment of expanded polystyrene (EPS) was performed. Subsequently, downward and upward flame spread experiments were conducted to analyze the appearance properties of EPS, flame temperature, mass loss rate, and flame spread rate at different light aging stages. Finally, based on the laws of energy conservation and mass conservation, two models were established to characterize the flame spread rates of downward and upward flame spread. The results showed that light aging led to morphology changes in EPS, such as yellowing of color and structural damage. Aging increased the values of multiple parameters such as flame temperatures, mass loss, and flame spread rate, indicating that light aging increased the fire risk. Especially, the models indicated that the flame spread rate had a nonlinear relationship with flame temperature and pyrolysis temperature.

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热塑性保温材料光老化后向下和向上火焰传播特性的研究
高层建筑中的热塑性隔热材料(TTIM)经常暴露在紫外线辐射、不同的温度和湿度环境中,导致轻度老化。它们的性能,如表面颜色和形态,都会发生变化,但其火灾风险却未见报道。特别是,TTIMs 的火灾危险性始终是高层建筑火灾的一个重要问题。因此,有必要对老化 TTIM 的火灾风险进行研究。我们对发泡聚苯乙烯(EPS)进行了加速老化试验。随后,进行了向下和向上火焰蔓延实验,分析了不同光老化阶段 EPS 的外观特性、火焰温度、质量损失率和火焰蔓延率。最后,根据能量守恒定律和质量守恒定律,建立了两个模型来表征向下和向上火焰蔓延的火焰蔓延率。结果表明,光老化导致发泡聚苯乙烯的形态发生变化,如颜色变黄和结构损坏。老化增加了火焰温度、质量损失和火焰蔓延率等多个参数值,表明轻度老化增加了火灾风险。特别是,模型表明火焰蔓延率与火焰温度和热解温度呈非线性关系。
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来源期刊
Journal of Applied Polymer Science
Journal of Applied Polymer Science 化学-高分子科学
CiteScore
5.70
自引率
10.00%
发文量
1280
审稿时长
2.7 months
期刊介绍: The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
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