A Proposal to Permanently Ban Flame Retardant Chemicals to Meet California’s Flammability Standard for Upholstered Furniture

IF 11.3 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL 环境科学与技术 Pub Date : 2025-04-22 DOI:10.1021/acs.est.5c03121
David C. Volz
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AB 2165 included a 141-word amendment to Section 19161 of the Business and Professions Code (BPC) requiring that “all mattresses manufactured for sale in this state ... shall be fire retardant” and “all upholstered furniture sold or offered for sale by a manufacturer or wholesaler for use in this state ... shall be fire retardant and shall be labeled in a manner specified by the bureau.” The Bureau of Electronic and Appliance Repair, Home Furnishings, and Thermal Insulation (now Bureau of Household Goods and Services) held jurisdictional authority over the furniture and bedding industries and were responsible for ensuring compliance with this new law. However, this amendment did not specify how mattresses and upholstered furniture “shall be fire retardant”. In 1973, the Federal Mattress Flammability Standard was simultaneously introduced by the U.S. Consumer Product Safety Commission (CPSC), allowing mattress manufacturers to immediately comply with California’s amendment to Section 19161 of the BPC. However, California was the only state that legally required that (1) upholstered furniture be fire retardant and (2) manufacturers affix permanent labels indicating compliance with state-specific flammability standards. As a result, this led to the implementation of an upholstered furniture flammability performance standard (Technical Bulletin 117, or TB117) in 1975, a deadline mandated by AB 2165. TB117 required that interior filling materials (e.g., polyurethane foam) of upholstered furniture be individually evaluated using open flame and cigarette smolder tests. In 2013, TB117 was revised (now TB117-2013) to address the potential ignition of upholstered cover fabric and interactions among different upholstered furniture components following exposure to smoldering ignition sources (i.e., cigarettes). Importantly, as a smolder-specific standard, TB117-2013 provides manufacturers the flexibility to use either flame retardant (FR) chemicals or barrier (interliner) materials to maintain compliance. Since 1975, TB117-compliant furniture has been sold across the entire United States to simplify production and distribution. As a result, TB117 has been the <i>de facto</i> flammability standard across the country since California was the only state that required upholstered furniture to be fire retardant. Moreover, the adoption of TB117 in the United States preceded fire safety regulations for upholstered furniture in the United Kingdom and Ireland in 1988, (1) suggesting that California-specific regulations initially exerted an influence on fire safety regulations and flammability standards within certain parts of Europe. However, the potential impact of California’s strict fire safety regulations on the rest of Europe and the world appears to have waned since the late 1980s, as there is currently a patchwork of fire safety regulations that vary in scope and stringency. (1) From 1975 to 2013, the addition of FR chemicals to interior filling materials of upholstered furniture was the primary approach to comply with TB117. Pentabrominated diphenyl ethers (PentaBDEs) were added to upholstered furniture from 1975 to the mid-2000s prior to being phased out in 2004 due to concerns about persistence, bioaccumulation, and toxicity within humans and the environment. As a result, formulations containing organophosphate esters (OPEs) were introduced as major alternatives to PentaBDEs in the mid-2000s and continue to be used today to maintain compliance with TB117-2013 and similar flammability standards around the world. As additive FR chemicals are not chemically bound to fabric or interior filling materials, these chemicals have the potential to migrate from upholstered furniture to indoor environmental media. Indeed, human exposure to additive flame retardants has, as a result of AB 2165, been chronic and ubiquitous across the United States for &gt;50 years, where indoor exposure was initially dominated by PentaBDEs from the mid-1970s to mid-2000s and then by OPEs from the mid-2000s to the present. (2) Moreover, relative to the general population, emergency personnel responding to structure fires continue to be at increased risk following ignition of FR chemical-containing furniture, (3) especially during large-scale wildfires at the wildland–urban interface such as the January 2025 fires within the Pacific Palisades and Altadena communities in southern California. The chemical industry has argued that the introduction of FR chemicals within upholstered furniture is necessary for delaying combustion and increasing escape time in the event of structure fires. (4) However, flammability studies conducted by the CPSC nearly 15 years ago demonstrate that (1) TB117-compliant foam treated with FR chemicals did not significantly decrease the rate of flame propagation of upholstered chairs compared to chairs that were not treated with FR chemicals and (2) incorporation of fiberglass- and modacrylic-containing fire barriers between the cover fabric and interior filling materials significantly decreased the rate of flame propagation of unholstered chairs regardless of fabric type and the presence or absence of FR chemicals in foam. (5) Motivated by CPSC’s findings, AB 2998 was introduced in the California State Assembly in 2018 to amend Section 19101 of the BPC and limit the concentration of FR chemicals added to consumer products. Effective January 1, 2020, AB 2998 prohibits the sale and distribution of juvenile products, mattresses, or upholstered furniture containing &gt;1000 ppm FR chemicals within California. Although the use of FR chemicals within upholstered furniture has declined over the past 10 years as a result of California’s regulations, (6) AB 2998 did not prohibit the use of FR chemicals despite CPSC’s data demonstrating that addition of FR chemicals to upholstered furniture did not provide an added benefit relative to fire barriers. Importantly, enacted in October 2023, AB 1059 amended Section 19101 of the BPC to ban fiberglass-containing fire barriers in California effective January 1, 2027, due to concerns about the potential for human inhalation of fiberglass fragments, raising the possibility that manufacturers may pivot back to FR chemicals (albeit at levels of ≤1000 ppm) to comply with TB117-2013. Therefore, the California State Assembly should, within their 2025–2026 or 2026–2027 session, introduce an Assembly Bill to further amend Section 19161 and/or Section 19101 of the BPC by including language that prohibits the use of FR chemicals at <i>any</i> concentration as a “fire retardant” to meet California’s flammability standard for upholstered furniture, as this will (1) prevent an increase in human and environmental exposure to FR chemicals resulting from enforcement of AB 1059-specific regulations in January 1, 2027, and (2) encourage the incorporation of commercially available, fiberglass-free fire barriers in upholstered furniture. For example, knitted or nonwoven barrier materials constructed from synthetic aramid or silica-infused rayon fibers are widely used to comply with existing mattress-specific flammability standards at the federal level, (7) suggesting that these materials may, in the future, have the potential to be utilized as fiberglass-free barriers within upholstered furniture to comply with TB117-2013. Dr. David C. Volz is a Professor within the Department of Environmental Sciences at the University of California, Riverside. Since transitioning from industry to academia in August 2009, Dr. Volz’s research program has focused on identifying the potential human health risks of chemical exposure and, as a result, promoting population-wide intervention and/or prevention strategies for mitigating human exposure to certain high-risk chemicals within California and across the United States. Dr. Volz has authored or co-authored more than 80 peer-reviewed papers and more than 200 presentations and invited seminars at numerous institutions and scientific meetings on topics ranging from toxicology to exposure science to risk assessment. Dr. Volz also received an Outstanding New Environmental Scientist (ONES) Award from the NIH’s National Institute of Environmental Health Sciences (NIEHS) in 2017, has served as an <i>ad hoc</i> reviewer on more than 20 special emphasis panels and study sections for NIH, and currently serves on a handful of editorial boards for journals focused on environmental science and toxicology. This article references 7 other publications. 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引用次数: 0

Abstract

In March 1972, Assembly Bill 2165 (AB 2165), a product safety-specific bill “relating to furniture and bedding”, was one of 2395 bills introduced in the California State Assembly and one of 896 bills enacted on January 1, 1973. AB 2165 was co-authored by Assemblymembers John Burton and Willie Brown who, from 1965 to 1974, represented the 20th and 18th districts, respectively, within San Francisco County. Based on the public record, it is unclear what compelled Burton and Brown to co-author AB 2165 during the 1972–1973 session. AB 2165 included a 141-word amendment to Section 19161 of the Business and Professions Code (BPC) requiring that “all mattresses manufactured for sale in this state ... shall be fire retardant” and “all upholstered furniture sold or offered for sale by a manufacturer or wholesaler for use in this state ... shall be fire retardant and shall be labeled in a manner specified by the bureau.” The Bureau of Electronic and Appliance Repair, Home Furnishings, and Thermal Insulation (now Bureau of Household Goods and Services) held jurisdictional authority over the furniture and bedding industries and were responsible for ensuring compliance with this new law. However, this amendment did not specify how mattresses and upholstered furniture “shall be fire retardant”. In 1973, the Federal Mattress Flammability Standard was simultaneously introduced by the U.S. Consumer Product Safety Commission (CPSC), allowing mattress manufacturers to immediately comply with California’s amendment to Section 19161 of the BPC. However, California was the only state that legally required that (1) upholstered furniture be fire retardant and (2) manufacturers affix permanent labels indicating compliance with state-specific flammability standards. As a result, this led to the implementation of an upholstered furniture flammability performance standard (Technical Bulletin 117, or TB117) in 1975, a deadline mandated by AB 2165. TB117 required that interior filling materials (e.g., polyurethane foam) of upholstered furniture be individually evaluated using open flame and cigarette smolder tests. In 2013, TB117 was revised (now TB117-2013) to address the potential ignition of upholstered cover fabric and interactions among different upholstered furniture components following exposure to smoldering ignition sources (i.e., cigarettes). Importantly, as a smolder-specific standard, TB117-2013 provides manufacturers the flexibility to use either flame retardant (FR) chemicals or barrier (interliner) materials to maintain compliance. Since 1975, TB117-compliant furniture has been sold across the entire United States to simplify production and distribution. As a result, TB117 has been the de facto flammability standard across the country since California was the only state that required upholstered furniture to be fire retardant. Moreover, the adoption of TB117 in the United States preceded fire safety regulations for upholstered furniture in the United Kingdom and Ireland in 1988, (1) suggesting that California-specific regulations initially exerted an influence on fire safety regulations and flammability standards within certain parts of Europe. However, the potential impact of California’s strict fire safety regulations on the rest of Europe and the world appears to have waned since the late 1980s, as there is currently a patchwork of fire safety regulations that vary in scope and stringency. (1) From 1975 to 2013, the addition of FR chemicals to interior filling materials of upholstered furniture was the primary approach to comply with TB117. Pentabrominated diphenyl ethers (PentaBDEs) were added to upholstered furniture from 1975 to the mid-2000s prior to being phased out in 2004 due to concerns about persistence, bioaccumulation, and toxicity within humans and the environment. As a result, formulations containing organophosphate esters (OPEs) were introduced as major alternatives to PentaBDEs in the mid-2000s and continue to be used today to maintain compliance with TB117-2013 and similar flammability standards around the world. As additive FR chemicals are not chemically bound to fabric or interior filling materials, these chemicals have the potential to migrate from upholstered furniture to indoor environmental media. Indeed, human exposure to additive flame retardants has, as a result of AB 2165, been chronic and ubiquitous across the United States for >50 years, where indoor exposure was initially dominated by PentaBDEs from the mid-1970s to mid-2000s and then by OPEs from the mid-2000s to the present. (2) Moreover, relative to the general population, emergency personnel responding to structure fires continue to be at increased risk following ignition of FR chemical-containing furniture, (3) especially during large-scale wildfires at the wildland–urban interface such as the January 2025 fires within the Pacific Palisades and Altadena communities in southern California. The chemical industry has argued that the introduction of FR chemicals within upholstered furniture is necessary for delaying combustion and increasing escape time in the event of structure fires. (4) However, flammability studies conducted by the CPSC nearly 15 years ago demonstrate that (1) TB117-compliant foam treated with FR chemicals did not significantly decrease the rate of flame propagation of upholstered chairs compared to chairs that were not treated with FR chemicals and (2) incorporation of fiberglass- and modacrylic-containing fire barriers between the cover fabric and interior filling materials significantly decreased the rate of flame propagation of unholstered chairs regardless of fabric type and the presence or absence of FR chemicals in foam. (5) Motivated by CPSC’s findings, AB 2998 was introduced in the California State Assembly in 2018 to amend Section 19101 of the BPC and limit the concentration of FR chemicals added to consumer products. Effective January 1, 2020, AB 2998 prohibits the sale and distribution of juvenile products, mattresses, or upholstered furniture containing >1000 ppm FR chemicals within California. Although the use of FR chemicals within upholstered furniture has declined over the past 10 years as a result of California’s regulations, (6) AB 2998 did not prohibit the use of FR chemicals despite CPSC’s data demonstrating that addition of FR chemicals to upholstered furniture did not provide an added benefit relative to fire barriers. Importantly, enacted in October 2023, AB 1059 amended Section 19101 of the BPC to ban fiberglass-containing fire barriers in California effective January 1, 2027, due to concerns about the potential for human inhalation of fiberglass fragments, raising the possibility that manufacturers may pivot back to FR chemicals (albeit at levels of ≤1000 ppm) to comply with TB117-2013. Therefore, the California State Assembly should, within their 2025–2026 or 2026–2027 session, introduce an Assembly Bill to further amend Section 19161 and/or Section 19101 of the BPC by including language that prohibits the use of FR chemicals at any concentration as a “fire retardant” to meet California’s flammability standard for upholstered furniture, as this will (1) prevent an increase in human and environmental exposure to FR chemicals resulting from enforcement of AB 1059-specific regulations in January 1, 2027, and (2) encourage the incorporation of commercially available, fiberglass-free fire barriers in upholstered furniture. For example, knitted or nonwoven barrier materials constructed from synthetic aramid or silica-infused rayon fibers are widely used to comply with existing mattress-specific flammability standards at the federal level, (7) suggesting that these materials may, in the future, have the potential to be utilized as fiberglass-free barriers within upholstered furniture to comply with TB117-2013. Dr. David C. Volz is a Professor within the Department of Environmental Sciences at the University of California, Riverside. Since transitioning from industry to academia in August 2009, Dr. Volz’s research program has focused on identifying the potential human health risks of chemical exposure and, as a result, promoting population-wide intervention and/or prevention strategies for mitigating human exposure to certain high-risk chemicals within California and across the United States. Dr. Volz has authored or co-authored more than 80 peer-reviewed papers and more than 200 presentations and invited seminars at numerous institutions and scientific meetings on topics ranging from toxicology to exposure science to risk assessment. Dr. Volz also received an Outstanding New Environmental Scientist (ONES) Award from the NIH’s National Institute of Environmental Health Sciences (NIEHS) in 2017, has served as an ad hoc reviewer on more than 20 special emphasis panels and study sections for NIH, and currently serves on a handful of editorial boards for journals focused on environmental science and toxicology. This article references 7 other publications. This article has not yet been cited by other publications.

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永久禁用阻燃化学品以满足加州软垫家具的可燃性标准的建议
1972 年 3 月,《2165 号众议院法案》(AB 2165)是一项 "与家具和床上用品有关 "的产品安全专项法案,是加州众议院提出的 2395 项法案之一,也是 1973 年 1 月 1 日颁布的 896 项法案之一。AB 2165法案由众议员约翰-伯顿(John Burton)和威利-布朗(Willie Brown)共同起草,他们在1965年至1974年期间分别代表旧金山县内的第20区和第18区。根据公开记录,目前尚不清楚是什么迫使伯顿和布朗在 1972-1973 年会议期间共同起草了 AB 2165 号法案。AB 2165 包括对《商业与职业法典》(BPC)第 19161 节的 141 个字的修订,要求 "所有在本州生产销售的床垫......均应具有阻燃性",以及 "所有由制造商或批发商销售或提供销售供本州使用的软垫家具......均应具有阻燃性,并应以该局规定的方式进行标注"。电子和电器维修、家居装饰和隔热局(现为家庭用品和服务局)对家具和床上用品行业拥有管辖权,并负责确保遵守这项新法律。然而,该修正案并未明确规定床垫和软垫家具 "应如何阻燃"。1973 年,美国消费品安全委员会(CPSC)同时出台了《联邦床垫可燃性标准》,允许床垫制造商立即遵守加利福尼亚州对《美国消费品安全委员会法案》第 19161 条的修订。然而,加利福尼亚州是唯一一个在法律上要求(1)软垫家具必须具有阻燃性;(2)制造商必须贴上永久性标签,表明符合该州特定的可燃性标准的州。因此,该州于 1975 年实施了软垫家具阻燃性能标准(第 117 号技术公告,简称 TB117),这是 AB 2165 规定的最后期限。TB117 要求对软垫家具的内部填充材料(如聚氨酯泡沫)使用明火和香烟燃烧测试进行单独评估。2013 年,对 TB117 进行了修订(即现在的 TB117-2013),以解决软垫外层织物的潜在点燃问题,以及不同软垫家具组件在暴露于烟熏火源(即香烟)后的相互作用问题。重要的是,作为一项专门针对烟熏的标准,TB117-2013 为制造商提供了使用阻燃 (FR) 化学品或阻隔(内衬)材料的灵活性,以保持合规性。自 1975 年以来,符合 TB117 标准的家具已在全美销售,以简化生产和分销。因此,TB117 已成为全美事实上的可燃性标准,因为加利福尼亚州是唯一一个要求软垫家具必须具有阻燃性的州。此外,TB117 在美国的采用早于 1988 年英国和爱尔兰的软垫家具防火安全法规,(1) 这表明加州的具体法规最初对欧洲某些地区的防火安全法规和易燃性标准产生了影响。然而,自 20 世纪 80 年代末以来,加利福尼亚州严格的消防安全法规对欧洲和世界其他地区的潜在影响似乎已经减弱,因为目前欧洲和世界其他地区的消防安全法规在范围和严格程度上不尽相同。(1) 从 1975 年到 2013 年,在软垫家具的内部填充材料中添加阻燃化学品是符合 TB117 标准的主要方法。从 1975 年到 2000 年代中期,五溴二苯醚(PentaBDEs)一直被添加到软垫家具中,后因担心其在人类和环境中的持久性、生物累积性和毒性而于 2004 年被逐步淘汰。因此,含有有机磷酸酯(OPE)的配方在 2000 年代中期作为五溴二苯醚的主要替代品问世,并一直沿用至今,以保持符合 TB117-2013 和世界各地类似的易燃性标准。由于添加型阻燃剂化学品不会与织物或室内填充材料发生化学结合,因此这些化学品有可能从软垫家具迁移到室内环境介质中。事实上,由于 AB 2165 法案的实施,50 年来,人类与添加型阻燃剂的接触在全美范围内长期存在且无处不在,其中,从 20 世纪 70 年代中期到 2000 年代中期,室内接触的主要是五溴二苯醚,而从 2000 年代中期到现在,接触的主要是 OPE。(2)此外,与普通人群相比,应对结构性火灾的应急人员在点燃含有 FR 化学品的家具后面临的风险继续增加,(3)尤其是在野地与城市交界处的大规模野火期间,例如 2025 年 1 月发生在南加州太平洋帕利塞德和阿尔塔迪纳社区的火灾。 化工行业认为,在软垫家具中引入阻燃化学品对于在结构性火灾中延缓燃烧和增加逃生时间是必要的。(4) 然而,美国消费品安全委员会(CPSC)近 15 年前进行的可燃性研究表明:(1) 与未使用阻燃剂的椅子相比,使用阻燃剂处理的符合 TB117 标准的泡沫并未显著降低软垫椅子的火焰蔓延速度;(2) 在覆盖织物和内部填充材料之间加入含玻璃纤维和丙烯酸酯的防火屏障,可显著降低无软垫椅子的火焰蔓延速度,而与织物类型和泡沫中是否含有阻燃剂无关。(5) 在消费品安全委员会调查结果的推动下,加利福尼亚州议会于 2018 年提出了 AB 2998 法案,以修订 BPC 第 19101 节,限制消费品中添加的阻燃剂浓度。从 2020 年 1 月 1 日起,AB 2998 法案禁止在加州销售和分销含有 1000 ppm FR 化学品的青少年产品、床垫或软垫家具。尽管在过去 10 年中,由于加利福尼亚州的规定,软垫家具中阻燃剂的使用量有所下降,(6) 但尽管美国消费品安全委员会的数据显示,在软垫家具中添加阻燃剂并不会带来比阻燃剂更多的益处,但 AB 2998 法案并未禁止使用阻燃剂。重要的是,由于担心人体吸入玻璃纤维碎片的可能性,AB 1059 于 2023 年 10 月颁布,修订了 BPC 第 19101 节,自 2027 年 1 月 1 日起禁止在加利福尼亚州使用含玻璃纤维的防火屏障,这使得制造商有可能重新使用玻璃纤维阻燃剂(尽管其含量≤1000 ppm)来符合 TB117-2013。因此,加利福尼亚州议会应在 2025-2026 年或 2026-2027 年的会议上提出一项议会法案,进一步修订《联邦防火法》第 19161 条和/或第 19101 条,加入禁止使用任何浓度的阻燃剂作为 "阻燃剂 "以满足加利福尼亚州软垫家具易燃性标准的规定、因为这将 (1) 防止因在 2027 年 1 月 1 日执行 AB 1059 具体法规而增加人类和环境对阻燃剂化学品的接触,以及 (2) 鼓励在软垫家具中使用市售的不含玻璃纤维的阻燃剂。例如,由合成芳纶或硅胶注入人造丝纤维制成的针织或无纺阻隔材料被广泛用于符合现有的联邦床垫易燃性标准,(7) 这表明这些材料将来有可能用作软垫家具中的无玻璃纤维阻隔材料,以符合 TB117-2013 标准。David C. Volz 博士是加州大学河滨分校环境科学系教授。自 2009 年 8 月从工业界转入学术界以来,Volz 博士的研究计划主要集中在识别化学品暴露对人类健康的潜在风险,并因此在加利福尼亚州和全美国推广全民干预和/或预防策略,以减少人类对某些高风险化学品的暴露。Volz 博士撰写或合著了 80 多篇经同行评审的论文,并在许多机构和科学会议上做了 200 多场演讲和受邀研讨会,主题涉及毒理学、暴露科学和风险评估。2017年,Volz博士还获得了美国国立卫生研究院国家环境健康科学研究所(NIEHS)颁发的杰出新环境科学家奖(ONES),并担任了美国国立卫生研究院20多个特别重点小组和研究部门的专职评审员,目前还在一些专注于环境科学和毒理学的期刊编委会任职。本文引用了 7 篇其他出版物。本文尚未被其他出版物引用。
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来源期刊
环境科学与技术
环境科学与技术 环境科学-工程:环境
CiteScore
17.50
自引率
9.60%
发文量
12359
审稿时长
2.8 months
期刊介绍: Environmental Science & Technology (ES&T) is a co-sponsored academic and technical magazine by the Hubei Provincial Environmental Protection Bureau and the Hubei Provincial Academy of Environmental Sciences. Environmental Science & Technology (ES&T) holds the status of Chinese core journals, scientific papers source journals of China, Chinese Science Citation Database source journals, and Chinese Academic Journal Comprehensive Evaluation Database source journals. This publication focuses on the academic field of environmental protection, featuring articles related to environmental protection and technical advancements.
期刊最新文献
Potassium Ferrate as a Novel Anti-Biofouling Agent for Invasive Freshwater Mussels: Multi-Omics Insights and Pilot-Scale Validation. Sorption of Anionic and Zwitterionic Per- and Polyfluoroalkyl Substances Present in Legacy Aqueous Film-Forming Foams Quantifying the Environmental Impacts and Human Health Risks of Global Cobalt Mining and Processing From the Road to the Field: Decoding Chemical Transformation in Aging Tire and Artificial Turf Crumb Rubber. Accounting for Exposure Measurement Error in Gridded Air Pollution Estimates in Assessing the Association of PM2.5 Exposures with Health Outcomes in Cohort Studies.
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