Effects of microstructure on the cracking behaviors in the lithium aluminosilicate glass ceramics: A statistical analysis

IF 3.5 3区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of Non-crystalline Solids Pub Date : 2025-07-15 Epub Date: 2025-04-23 DOI:10.1016/j.jnoncrysol.2025.123559
Ping Lu , Jingxi Chen , Yu Rao , Jialin Cui , Yinsheng Xu , Mengling Xia , Dong Wu , Guanchao Yin
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Abstract

The cracking behaviors of transparent glass ceramics have attracted much attention due to the application as a cover material for smartphones, and it is beneficial to fundamentally understand their origin. In this study, the cracks were induced by scratch and indentation, and their occurrence has been analyzed according to the Weibull’s statistical model. The roles of microstructure on the initiations and propagations of cracks were discussed in terms of modeling parameters, which provided hints for the cracking mechanisms. Overall, it was found that crystallization contributed to the formation of cracks, which seems to be inconsistent with the common sense that crystallites in glass ceramics hinder the cracking. According to the statistical analysis, the critical stress or load for crack initiation is suggested to drop due to the residual stress introduced by crystallization, while the crack propagation is still impeded by the crystalline phases and brings up the fracture toughness (KIC).
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微观结构对铝硅酸盐锂玻璃陶瓷开裂行为的影响:统计分析
透明玻璃陶瓷作为智能手机的外壳材料,其开裂行为备受关注,有助于从根本上了解其起源。在本研究中,裂纹是由划痕和压痕引起的,并根据Weibull统计模型对其发生进行了分析。从模型参数的角度讨论了微观结构对裂纹萌生和扩展的影响,为裂纹机理的研究提供了线索。总的来说,我们发现结晶有助于裂纹的形成,这似乎与玻璃陶瓷中的晶体阻碍裂纹的常识不一致。统计分析表明,由于结晶过程中引入的残余应力,裂纹萌生的临界应力或载荷有所下降,但裂纹扩展仍受到结晶相的阻碍,从而提高了断裂韧性(KIC)。
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来源期刊
Journal of Non-crystalline Solids
Journal of Non-crystalline Solids 工程技术-材料科学:硅酸盐
CiteScore
6.50
自引率
11.40%
发文量
576
审稿时长
35 days
期刊介绍: The Journal of Non-Crystalline Solids publishes review articles, research papers, and Letters to the Editor on amorphous and glassy materials, including inorganic, organic, polymeric, hybrid and metallic systems. Papers on partially glassy materials, such as glass-ceramics and glass-matrix composites, and papers involving the liquid state are also included in so far as the properties of the liquid are relevant for the formation of the solid. In all cases the papers must demonstrate both novelty and importance to the field, by way of significant advances in understanding or application of non-crystalline solids; in the case of Letters, a compelling case must also be made for expedited handling.
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