Photoinduced Copper-Catalyzed N-Arylation Reaction of NH Heteroarenes Using Aryl Thianthrenium Salts

IF 2.7 3区 化学 Q2 CHEMISTRY, ORGANIC European Journal of Organic Chemistry Pub Date : 2025-04-22 DOI:10.1002/ejoc.202500303
Zhenhui Wang, Qianqian Yang, Lan Bao, Ruiyun Zhang, Mingming Gao, Wei Liu
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Abstract

Herein, an efficient photoinduced copper-catalyzed N-arylation reaction is presented, which occurs through the cross-coupling of NH heteroarenes with aryl thianthrenium salts (Ar-TTs). This photoactivation strategy exhibits broad substrate scope and offers a method for preserving activated functional groups (such as Br, CHO, and CN) for subsequent derivatization reactions.

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利用芳基硫鎓盐光诱导N-H杂芳烃的n -芳基化反应
在这里,我们提出了一个有效的光诱导铜催化的n -芳基化反应,通过N-H杂芳烃与芳基硫鎓盐(Ar-TTs)的交叉偶联发生。这种光激活策略显示出广泛的底物范围,并提供了一种保留活化官能团(如Br, CHO和CN)用于后续衍生化的方法。
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来源期刊
CiteScore
5.40
自引率
3.60%
发文量
752
审稿时长
1 months
期刊介绍: The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.
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