Green preparation of lightweight and elastic poly (butylene adipate-co-terephthalate)/thermoplastic polyamide elastomer composite foams

IF 4.4 3区 工程技术 Q2 CHEMISTRY, PHYSICAL Journal of Supercritical Fluids Pub Date : 2025-09-01 Epub Date: 2025-04-21 DOI:10.1016/j.supflu.2025.106635
Xuelin Zhang, Peiying Yue, Xiulu Gao, Yichong Chen, Ling Zhao, Dongdong Hu
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Abstract

This work aims to prepare biodegradable poly (butylene adipate-co-terephthalate) (PBAT)/thermoplastic polyamide elastomer (TPAE) foam with excellent mechanical properties after blending and chain extension. The results showed that the introduction of TPAE increased the foaming temperature of the PBAT/TPAE blend foams, improved the foaming performance, reduced the shrinkage, and enhanced the compressive stress. The stable expansion ratio of PBAT/TPAE10 increased to 15.2 at 110 ℃, and the shrinkage ratio just reached 54.9 %. The energy loss coefficient of PBAT/TPAE at a high expansion ratio of 10 is 7.8 %. The resilience of PBAT/TPAE20 reached 61.3 % at an expansion ratio of 14.
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绿色制备轻质弹性聚己二酸丁二酯/热塑性聚酰胺弹性体复合泡沫
本研究旨在通过共混和扩链制备具有优异力学性能的可生物降解聚己二酸丁二酯(PBAT)/热塑性聚酰胺弹性体(TPAE)泡沫材料。结果表明:TPAE的加入提高了PBAT/TPAE共混泡沫的发泡温度,改善了发泡性能,降低了收缩率,增强了压应力;在110℃时,PBAT/TPAE10的稳定膨胀率提高到15.2,收缩率刚刚达到54.9 %。PBAT/TPAE在高膨胀比为10时的能量损失系数为7.8% %。当膨胀比为14时,PBAT/TPAE20的回弹性达到61.3 %。
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来源期刊
Journal of Supercritical Fluids
Journal of Supercritical Fluids 工程技术-工程:化工
CiteScore
7.60
自引率
10.30%
发文量
236
审稿时长
56 days
期刊介绍: The Journal of Supercritical Fluids is an international journal devoted to the fundamental and applied aspects of supercritical fluids and processes. Its aim is to provide a focused platform for academic and industrial researchers to report their findings and to have ready access to the advances in this rapidly growing field. Its coverage is multidisciplinary and includes both basic and applied topics. Thermodynamics and phase equilibria, reaction kinetics and rate processes, thermal and transport properties, and all topics related to processing such as separations (extraction, fractionation, purification, chromatography) nucleation and impregnation are within the scope. Accounts of specific engineering applications such as those encountered in food, fuel, natural products, minerals, pharmaceuticals and polymer industries are included. Topics related to high pressure equipment design, analytical techniques, sensors, and process control methodologies are also within the scope of the journal.
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