Aleksandra Ziółkowska, Wiktoria Błaszkiewicz and Tomasz Kruczyński
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引用次数: 0
Abstract
A new lithium salt of diphosphane, (iPr2N)PhP–P(SiMe3)Li (2), featuring two substituents with distinct electronic characterstics, is reported. A subsequent reaction of the compound 2 with benzophenone was yielded a novel phosphanylphosphaalkene (3). The isolated compound was subsequently treated with nBuLi and PhLi to obtain stable activators (3a and 3b) for the potential polymerization of phosphorus-rich compounds.
期刊介绍:
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.