{"title":"Intermediates in the neutral photolysis of riboflavin.","authors":"M S Jorns, P Hemmerich","doi":"10.1515/znb-1972-0910","DOIUrl":null,"url":null,"abstract":"The formation of a species with an absorption maximum around 410 nm, observed during the neutral photolysis of 10-(2'-hydroxyalkyl) flavins by earlier authors, is shown to depend on the presence of divalent anions. The structure of this new type of compounds is presented and a possible mechanism for the reaction is discussed.","PeriodicalId":78857,"journal":{"name":"Zeitschrift fur Naturforschung. Teil B. Anorganische Chemie, organische Chemie, Biochemie, Biophysik, Biologie","volume":"27 9","pages":"1040-4"},"PeriodicalIF":0.0000,"publicationDate":"1972-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/znb-1972-0910","citationCount":"7","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift fur Naturforschung. Teil B. Anorganische Chemie, organische Chemie, Biochemie, Biophysik, Biologie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1515/znb-1972-0910","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 7
Abstract
The formation of a species with an absorption maximum around 410 nm, observed during the neutral photolysis of 10-(2'-hydroxyalkyl) flavins by earlier authors, is shown to depend on the presence of divalent anions. The structure of this new type of compounds is presented and a possible mechanism for the reaction is discussed.