Surface-coordinated metal-organic framework thin films (SURMOFs): From fabrication to energy applications

IF 22.2 Q1 CHEMISTRY, MULTIDISCIPLINARY EnergyChem Pub Date : 2021-11-01 DOI:10.1016/j.enchem.2021.100065
Yi-Hong Xiao , Yi-Bo Tian , Zhi-Gang Gu , Jian Zhang
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引用次数: 17

Abstract

The development of clean and sustainable energy is crucial to solve the increasingly serious energy crisis. Metal-organic frameworks (MOFs) containing both inorganic and organic components have attracted extensive attention on energy applications because of their tunable structures and fascinating properties. Particularly, liquid-phase epitaxial (LPE) layer by layer (LBL) growth of MOFs thin films on various substrates surfaces (called SURMOFs, surface-coordinated MOF thin films) possess the advantages of controlled thickness, preferred growth orientation and homogeneous film, which provide ideal candidates for energy storage and conversion. In this review, we summarize the fabrication strategies of SURMOFs including the layer by layer dipping, pump, spray, spin-coating and flowing methods, the classification and advantages of SURMOFs, and then discuss the related energy applications of SURMOFs, encapsulated SURMOFs, and SURMOF-derivative on electrocatalysis, photocatalysis, and solar cells etc.

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表面配位金属有机框架薄膜(SURMOFs):从制造到能源应用
发展清洁、可持续的能源是解决日益严重的能源危机的关键。含有有机和无机成分的金属有机骨架(MOFs)由于其结构可调和优异的性能在能源应用方面引起了广泛的关注。特别是在各种衬底表面上的MOF薄膜(称为surmof,表面协调MOF薄膜)的液相外延(LPE)层接层(LBL)生长具有厚度可控、生长取向优越和薄膜均匀等优点,为能量存储和转换提供了理想的候选材料。本文综述了SURMOFs的制备方法,包括逐层浸渍法、泵法、喷雾法、旋涂法和流动法,SURMOFs的分类和优点,讨论了SURMOFs、封装SURMOFs及其衍生物在电催化、光催化和太阳能电池等领域的相关能源应用。
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来源期刊
EnergyChem
EnergyChem Multiple-
CiteScore
40.80
自引率
2.80%
发文量
23
审稿时长
40 days
期刊介绍: EnergyChem, a reputable journal, focuses on publishing high-quality research and review articles within the realm of chemistry, chemical engineering, and materials science with a specific emphasis on energy applications. The priority areas covered by the journal include:Solar energy,Energy harvesting devices,Fuel cells,Hydrogen energy,Bioenergy and biofuels,Batteries,Supercapacitors,Electrocatalysis and photocatalysis,Energy storage and energy conversion,Carbon capture and storage
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