Metallacycle/metallacage-cored supramolecular networks

IF 26 1区 化学 Q1 POLYMER SCIENCE Progress in Polymer Science Pub Date : 2023-06-01 DOI:10.1016/j.progpolymsci.2023.101680
Ruoqian Zhang , Rongrong Li , Feihe Huang , Mingming Zhang
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引用次数: 1

Abstract

Supramolecular networks often possess good dynamic features but suffer from low mechanical properties. Supramolecular coordination complexes including metallacycles and metallacages have rigid chemical structures and tunable cavities but often lack processability. Therefore, the reasonable integration of these two types of supramolecular structures into metallacycle/metallacage-cored supramolecular networks will reduce the shortcomings of both structures and offer intriguing properties for diverse applications. This review summarizes the progress of metallacycle/metallacage-cored networks according to the covalent or non-covalent interactions used to connect these metallacycles and metallacages. In each part, the structures, properties, functions and applications of such supramolecular networks are described in detail, in order to demonstrate the most exciting achievements in this emerging area. The remaining challenges and perspectives are also given at the end of this review. We hope this review can give our readers a snapshot on metallacycle/metallacage-cored supramolecular networks and attract more scientists to devote into this promising field.

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金属环/金属包芯超分子网络
超分子网络通常具有良好的动态特性,但力学性能较低。金属环和金属镀层等超分子配位配合物具有刚性的化学结构和可调的空腔,但往往缺乏可加工性。因此,将这两种类型的超分子结构合理地整合到金属环/金属包芯的超分子网络中,将减少这两种结构的缺点,并为各种应用提供有趣的性能。本文根据连接金属环和金属包层的共价或非共价相互作用,综述了金属环/金属包层网络的研究进展。在每一部分中,详细描述了这种超分子网络的结构、性质、功能和应用,以展示这一新兴领域最令人兴奋的成就。本文最后还提出了未来的挑战和展望。我们希望这篇综述能给我们的读者一个关于金属循环/金属核超分子网络的快照,并吸引更多的科学家投入到这个有前途的领域。
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来源期刊
Progress in Polymer Science
Progress in Polymer Science 化学-高分子科学
CiteScore
48.70
自引率
1.10%
发文量
54
审稿时长
38 days
期刊介绍: Progress in Polymer Science is a journal that publishes state-of-the-art overview articles in the field of polymer science and engineering. These articles are written by internationally recognized authorities in the discipline, making it a valuable resource for staying up-to-date with the latest developments in this rapidly growing field. The journal serves as a link between original articles, innovations published in patents, and the most current knowledge of technology. It covers a wide range of topics within the traditional fields of polymer science, including chemistry, physics, and engineering involving polymers. Additionally, it explores interdisciplinary developing fields such as functional and specialty polymers, biomaterials, polymers in drug delivery, polymers in electronic applications, composites, conducting polymers, liquid crystalline materials, and the interphases between polymers and ceramics. The journal also highlights new fabrication techniques that are making significant contributions to the field. The subject areas covered by Progress in Polymer Science include biomaterials, materials chemistry, organic chemistry, polymers and plastics, surfaces, coatings and films, and nanotechnology. The journal is indexed and abstracted in various databases, including Materials Science Citation Index, Chemical Abstracts, Engineering Index, Current Contents, FIZ Karlsruhe, Scopus, and INSPEC.
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