Residue dynamics of acephate and methamidophos in urban dooryard citrus foliage, Pompano Beach, Florida--August-September 1978.

Pesticides monitoring journal Pub Date : 1980-06-01
G E Fitzpatrick, M D Bogan
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Abstract

Residues of acephate and its toxic metabolite methamidophos, attributable to the State-Federal program for eradication of the citrus blackfly (CBF) [Aleurocanthus woglumi Ashby] on citrus foliage, were assessed in urban areas in Pompano Beach, Florida. Eighteen dooryard citrus trees were sampled on two line transects, each ca 1.6 km long, along two city streets. The trees were sampled twice monthly for five months, beginning before chemical treatments were applied, continuing through the acephate treatment period, and ending when residues decreased below the limits of detection. Acephate and methamidophos residues, as high as 302.5 ppm and 15.8 ppm, respectively, were detected on leaves within one day after the first of a series of three treatments. Significant conversion of acephate to methamidophose was observed. Of the 143 samples collected, 114 contained measurable residues of both compounds; methamidophos accounted for an average of 19 percent of the total residues. Both compounds degraded rapidly, however, and residues averaged below 1 ppm approximately four weeks after the third treatment in the series. Average foliar half-lives for acephate and methamidophos were 8.93 days (SD = 2.52) and 8.40 days (SD = 2.55), respectively.

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1978年8月至9月,佛罗里达州庞帕诺海滩城市庭院柑橘叶中甲胺磷和甲胺磷的残留动态。
对佛罗里达州庞帕诺海滩市区柑橘叶上的甲胺磷及其有毒代谢物残留进行了评估,这可归功于州-联邦根除柑橘黑蝇(CBF) [Aleurocanthus woglumi Ashby]计划。沿着两条城市街道,在两条横线上取样18棵庭院柑橘树,每条横线长约1.6公里。每个月采样两次,持续五个月,从施用化学处理之前开始,持续到乙酰甲胺磷处理期间,直到残留量降至检测限度以下。在连续三次处理的第一次处理后一天内,在叶片上检测到的甲胺磷和甲胺磷残留量分别高达302.5 ppm和15.8 ppm。观察到甲胺磷显著转化为甲胺磷。在收集的143个样本中,114个含有可测量的这两种化合物的残留;甲胺磷平均占总残留量的19%。然而,这两种化合物降解迅速,在该系列的第三次处理后大约四周,残留物平均低于1ppm。甲胺磷和甲胺磷的平均叶半衰期分别为8.93天(SD = 2.52)和8.40天(SD = 2.55)。
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