Yasong Zhao , Nailiang Yang , Ranbo Yu , Yue Zhang , Jin Zhang , Yuliang Li , Dan Wang
{"title":"Unique structural advances of graphdiyne for energy applications","authors":"Yasong Zhao , Nailiang Yang , Ranbo Yu , Yue Zhang , Jin Zhang , Yuliang Li , Dan Wang","doi":"10.1016/j.enchem.2020.100041","DOIUrl":null,"url":null,"abstract":"<div><p><span>Different from other carbon allotropes, graphdiyne (GDY) features topological sp- and sp</span><sup>2</sup><span>-hybridized carbon atoms. With the unique structural advances, a charming electronic behavior has been presented by GDY, which has shown great improvement for various energy-related fields. Inspired by this, it is time to summarize the structure-induced property enhancement. Firstly, different stacking configurations in GDY can induce specific electronic properties, bringing promising energy application<span>. Secondly, uniform pores provide enough sites for anchoring atoms and nanoparticles, enriching the diversity of materials. Thirdly, the sufficient alkynyl groups offer active sites for doping and grafting, providing possibilities for the precise design at the molecular level. Lastly, we propose some perspectives for future trends on GDY. Through this review, we hope to provide a guideline for rational design on GDY-based materials and reveal the structure-performance relationship between functionalized GDY and energy conversion/storage.</span></span></p></div>","PeriodicalId":307,"journal":{"name":"EnergyChem","volume":"2 5","pages":"Article 100041"},"PeriodicalIF":22.2000,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.enchem.2020.100041","citationCount":"37","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"EnergyChem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2589778020300166","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 37
Abstract
Different from other carbon allotropes, graphdiyne (GDY) features topological sp- and sp2-hybridized carbon atoms. With the unique structural advances, a charming electronic behavior has been presented by GDY, which has shown great improvement for various energy-related fields. Inspired by this, it is time to summarize the structure-induced property enhancement. Firstly, different stacking configurations in GDY can induce specific electronic properties, bringing promising energy application. Secondly, uniform pores provide enough sites for anchoring atoms and nanoparticles, enriching the diversity of materials. Thirdly, the sufficient alkynyl groups offer active sites for doping and grafting, providing possibilities for the precise design at the molecular level. Lastly, we propose some perspectives for future trends on GDY. Through this review, we hope to provide a guideline for rational design on GDY-based materials and reveal the structure-performance relationship between functionalized GDY and energy conversion/storage.
期刊介绍:
EnergyChem, a reputable journal, focuses on publishing high-quality research and review articles within the realm of chemistry, chemical engineering, and materials science with a specific emphasis on energy applications. The priority areas covered by the journal include:Solar energy,Energy harvesting devices,Fuel cells,Hydrogen energy,Bioenergy and biofuels,Batteries,Supercapacitors,Electrocatalysis and photocatalysis,Energy storage and energy conversion,Carbon capture and storage