{"title":"The complex nonstoichiometry of wüstite Fe1-zO: Review and comments","authors":"Jean-Raymond Gavarri , Claude Carel","doi":"10.1016/j.progsolidstchem.2018.10.001","DOIUrl":null,"url":null,"abstract":"<div><p>Thermodynamic properties and structural aspects of the nonstoichiometric wüstite Fe<sub>1-<strong><em>z</em></strong></sub>O, and its modifications - the so-called pseudo-phases - as functions of departure <strong><em>z</em></strong><span> from stoichiometry<span><span> and of equilibrium temperature are reviewed from 1960 to present. The complexity of the equilibrium phase diagram is described in some details. The first order transition W ⇆ W′ is specified on the iron/wüstite boundary near 1185 K. Transitions correlated to the modifications Wi at T(W) > 1185 K and W'j at T(W′) < 1185 K (i and j = 1,2,3) are re-examined. Structural determinations based on the characterization of </span>point defects stabilization and of their clustering are reviewed. Additionally, the pseudo-phases are examined based on the transformation of defect clusters or of their mode of distribution (</span></span><em>i.e.,</em><span> percolation or superstructure) with the inclusion of changes in electronic charge carriers.</span></p></div>","PeriodicalId":415,"journal":{"name":"Progress in Solid State Chemistry","volume":"53 ","pages":"Pages 27-49"},"PeriodicalIF":9.1000,"publicationDate":"2019-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.progsolidstchem.2018.10.001","citationCount":"12","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Solid State Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0079678618300281","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 12
Abstract
Thermodynamic properties and structural aspects of the nonstoichiometric wüstite Fe1-zO, and its modifications - the so-called pseudo-phases - as functions of departure z from stoichiometry and of equilibrium temperature are reviewed from 1960 to present. The complexity of the equilibrium phase diagram is described in some details. The first order transition W ⇆ W′ is specified on the iron/wüstite boundary near 1185 K. Transitions correlated to the modifications Wi at T(W) > 1185 K and W'j at T(W′) < 1185 K (i and j = 1,2,3) are re-examined. Structural determinations based on the characterization of point defects stabilization and of their clustering are reviewed. Additionally, the pseudo-phases are examined based on the transformation of defect clusters or of their mode of distribution (i.e., percolation or superstructure) with the inclusion of changes in electronic charge carriers.
期刊介绍:
Progress in Solid State Chemistry offers critical reviews and specialized articles written by leading experts in the field, providing a comprehensive view of solid-state chemistry. It addresses the challenge of dispersed literature by offering up-to-date assessments of research progress and recent developments. Emphasis is placed on the relationship between physical properties and structural chemistry, particularly imperfections like vacancies and dislocations. The reviews published in Progress in Solid State Chemistry emphasize critical evaluation of the field, along with indications of current problems and future directions. Papers are not intended to be bibliographic in nature but rather to inform a broad range of readers in an inherently multidisciplinary field by providing expert treatises oriented both towards specialists in different areas of the solid state and towards nonspecialists. The authorship is international, and the subject matter will be of interest to chemists, materials scientists, physicists, metallurgists, crystallographers, ceramists, and engineers interested in the solid state.