Study of optical and conducting properties of FeCl3 doped PVA polymers

IF 4.5 2区 材料科学 Q1 CRYSTALLOGRAPHY Progress in Crystal Growth and Characterization of Materials Pub Date : 2014-09-01 DOI:10.1016/j.pcrysgrow.2014.09.003
G. Thejas Urs , Radhika V. Hurkadli , R.V. Basavaraj , M. Niranjana , A. Manjunath , R. Somashekar
{"title":"Study of optical and conducting properties of FeCl3 doped PVA polymers","authors":"G. Thejas Urs ,&nbsp;Radhika V. Hurkadli ,&nbsp;R.V. Basavaraj ,&nbsp;M. Niranjana ,&nbsp;A. Manjunath ,&nbsp;R. Somashekar","doi":"10.1016/j.pcrysgrow.2014.09.003","DOIUrl":null,"url":null,"abstract":"<div><p>In the present work, PVA and various concentrations of FeCl<sub>3</sub> doped PVA polymer were prepared and optical studies like IR and UV/Visible analysis were carried out on them in solution form also the cast films were examined for their conductance. The variation of optical band gap of PVA polymer with the addition of Fe<sup>3+</sup><span> transition metal ion<span> has been determined by the Tauc plot method. It is found that the optical band gap and the transmittance<span> of the polymer solutions being decreased with the increase in the concentration of Fe</span></span></span><sup>3+</sup><span> ion, and thus obeys Beer's Law. This is supported by conductivity obtained for these polymers and FT-IR spectra which shows the stretching of the various bonds of the polymer due to the addition of transition metal (Fe</span><sup>3+</sup>) ions.</p></div>","PeriodicalId":409,"journal":{"name":"Progress in Crystal Growth and Characterization of Materials","volume":null,"pages":null},"PeriodicalIF":4.5000,"publicationDate":"2014-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.pcrysgrow.2014.09.003","citationCount":"17","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Crystal Growth and Characterization of Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0960897414000254","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 17

Abstract

In the present work, PVA and various concentrations of FeCl3 doped PVA polymer were prepared and optical studies like IR and UV/Visible analysis were carried out on them in solution form also the cast films were examined for their conductance. The variation of optical band gap of PVA polymer with the addition of Fe3+ transition metal ion has been determined by the Tauc plot method. It is found that the optical band gap and the transmittance of the polymer solutions being decreased with the increase in the concentration of Fe3+ ion, and thus obeys Beer's Law. This is supported by conductivity obtained for these polymers and FT-IR spectra which shows the stretching of the various bonds of the polymer due to the addition of transition metal (Fe3+) ions.

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
FeCl3掺杂PVA聚合物的光学和导电性能研究
在本工作中,制备了PVA和不同浓度的FeCl3掺杂PVA聚合物,并在溶液形式下对它们进行了红外和紫外/可见分析等光学研究,并对铸膜进行了电导测试。用Tauc图法测定了Fe3+过渡金属离子加入后PVA聚合物光学带隙的变化。研究发现,随着Fe3+离子浓度的增加,聚合物溶液的光学带隙和透射率减小,符合比尔定律。这得到了这些聚合物的电导率和FT-IR光谱的支持,该光谱显示了由于添加过渡金属(Fe3+)离子而导致聚合物的各种键的拉伸。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Progress in Crystal Growth and Characterization of Materials
Progress in Crystal Growth and Characterization of Materials 工程技术-材料科学:表征与测试
CiteScore
8.80
自引率
2.00%
发文量
10
审稿时长
1 day
期刊介绍: Materials especially crystalline materials provide the foundation of our modern technologically driven world. The domination of materials is achieved through detailed scientific research. Advances in the techniques of growing and assessing ever more perfect crystals of a wide range of materials lie at the roots of much of today''s advanced technology. The evolution and development of crystalline materials involves research by dedicated scientists in academia as well as industry involving a broad field of disciplines including biology, chemistry, physics, material sciences and engineering. Crucially important applications in information technology, photonics, energy storage and harvesting, environmental protection, medicine and food production require a deep understanding of and control of crystal growth. This can involve suitable growth methods and material characterization from the bulk down to the nano-scale.
期刊最新文献
Electrospray crystallization: A review on submicrometric and nanosized crystal synthesis Editorial Board The equation of life in the Universe: Biomorphs as reminiscence of the first forms of life Defect selective photoetching of GaN: Progress, applications and prospects The equation of the origin of life in the Universe (Part II): The combination of chemical elements does not determine the emergence of life on Earth
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1