Modeling and analysis of pumping cell of NOx sensor – Part II: NOx pumping cell

IF 8 1区 化学 Q1 CHEMISTRY, ANALYTICAL Sensors and Actuators B: Chemical Pub Date : 2022-12-15 DOI:10.1016/j.snb.2022.132658
Zhen Wang , Zhong-hua Deng , Jie Wang , Wei-xun Lin , Xiao-wei Fu , Xi Li
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Abstract

To improve the performance of the NOx sensor, a combined model based on the electrochemical model and the diffusion model is developed for the NOx pumping cell of the NOx sensor. Considering that a small amount of oxygen enters the third chamber and part of NO is decomposed in the second chamber, the reactions of both NO and oxygen at cathode are taken into account in the electrochemical model, and the diffusion model additionally takes the diffusion of oxygen and the decomposition of NO into consideration. To validate the model at different gas concentrations, the sensor is mounted on the designed test rig. Then, the simulation results are compared with experimental data from the test rig and good agreement is obtained. In addition, three key parameters in the model of the NOx pumping cell are analyzed. The values and changing trends of these three parameters are given in the paper.

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氮氧化物传感器泵送单元的建模和分析。第二部分:氮氧化物泵送单元
为了提高NOx传感器的性能,建立了基于电化学模型和扩散模型的NOx泵送电池组合模型。考虑到少量氧气进入第三腔室,部分NO在第二腔室分解,电化学模型中同时考虑了阴极处NO和氧气的反应,扩散模型中还考虑了氧气的扩散和NO的分解。为了在不同气体浓度下验证模型,将传感器安装在设计的测试台上。然后,将仿真结果与试验台的实验数据进行了比较,得到了较好的一致性。此外,还分析了NOx抽吸池模型中的三个关键参数。文中给出了这三个参数的取值及其变化趋势。
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来源期刊
Sensors and Actuators B: Chemical
Sensors and Actuators B: Chemical 工程技术-电化学
CiteScore
14.60
自引率
11.90%
发文量
1776
审稿时长
3.2 months
期刊介绍: Sensors & Actuators, B: Chemical is an international journal focused on the research and development of chemical transducers. It covers chemical sensors and biosensors, chemical actuators, and analytical microsystems. The journal is interdisciplinary, aiming to publish original works showcasing substantial advancements beyond the current state of the art in these fields, with practical applicability to solving meaningful analytical problems. Review articles are accepted by invitation from an Editor of the journal.
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