[Three new polyhydroxysteroids from the tropical starfish Asteropsis carinifera].

Bioorganicheskaia khimiia Pub Date : 2010-11-01
T V Maliarenko, A A Kicha, N V Ivanchina, A I Kalinovskiĭ, P S Dmitrenok, A V Smirnov
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Abstract

Thirteen steroidal compounds including three new polyhydroxysteroids, (24R,25S)-24-methyl-5α-cholestane-3β,6α,8,15β,16β,26-hexaol, (22E,24R,25S)-24-methyl-5α-cholest-22-ene-3β,6α,8,15β,16β,26-hexaol and (22E,24R,25S)-24-methyl-5α-cholest-22-ene-3β,4β,6α,8,15β,16β,26-heptaol, have been isolated along with the previously known ten polyhydroxysteroids from the tropical starfish Asteropsis carinifera collected near the coast of Vietnam. The structures of new compounds were elucidated by spectroscopic methods (mainly 2D NMR and ESI-mass-spectrometry).

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[从热带海星Asteropsis carinifera中提取的三种新的多羟基类固醇]。
从越南沿海采集的热带海星Asteropsis carinifera中分离到13种甾体化合物,包括3种新的多羟基类固醇(24R,25S)-24-甲基-5α-胆甾-3β,6α,8,15β,16β, 16β,26-己醇,(22E,24R,25S)-24-甲基-5α-胆甾-22-烯-3β,6α,8,15β,16β,26-七醇和(22E,24R,25S)-24-甲基-5α-胆甾-22-烯-3β,4β,6α,8,15β,16β,26-七醇。用波谱方法(主要是二维核磁共振和esi质谱)对新化合物的结构进行了鉴定。
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