Multifunctional porous aromatic frameworks: State of the art and opportunities

IF 22.2 Q1 CHEMISTRY, MULTIDISCIPLINARY EnergyChem Pub Date : 2020-09-01 DOI:10.1016/j.enchem.2020.100037
Ye Yuan, Yajie Yang, Guangshan Zhu
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引用次数: 26

Abstract

Porous aromatic frameworks (PAFs) are amorphous porous materials that are known for their large surface area, versatile structure, and high thermal/chemical stability. PAFs are constructed via a bottom-up approach from rigid organic building units that have a predesigned geometry and are connected through irreversible CC bonds. Due to their intriguing and tailorable structures, PAFs are widely deployed in catalysis, ion/molecule storage, and many other valuable applications. This review summarizes the recent progress on PAFs and PAF derivatives, including their design, synthesis, and applications. We conduct a detailed correlation investigation between the structural and chemical features of PAFs and their potential functions. The significant advantages (and disadvantages) and opportunities of PAFs are also discussed for the development of next-generation porous materials in the future for practical applications.

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多功能多孔芳香框架:现状和机遇
多孔芳香骨架(paf)是一种非晶多孔材料,以其大表面积、多用途结构和高热/化学稳定性而闻名。paf是由刚性有机建筑单元自下而上构建的,这些单元具有预先设计的几何形状,并通过不可逆的C - C键连接。由于其有趣和可定制的结构,paf被广泛应用于催化、离子/分子存储和许多其他有价值的应用。本文综述了PAF及其衍生物的设计、合成和应用等方面的研究进展。我们对paf的结构和化学特征及其潜在功能进行了详细的相关性研究。讨论了paf的显著优点(缺点)和机会,为未来开发下一代多孔材料的实际应用提供了参考。
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来源期刊
EnergyChem
EnergyChem Multiple-
CiteScore
40.80
自引率
2.80%
发文量
23
审稿时长
40 days
期刊介绍: EnergyChem, a reputable journal, focuses on publishing high-quality research and review articles within the realm of chemistry, chemical engineering, and materials science with a specific emphasis on energy applications. The priority areas covered by the journal include:Solar energy,Energy harvesting devices,Fuel cells,Hydrogen energy,Bioenergy and biofuels,Batteries,Supercapacitors,Electrocatalysis and photocatalysis,Energy storage and energy conversion,Carbon capture and storage
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